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《Chinese Journal of Analytical Chemistry》 2010-05
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Preparation and Application of Atrazine Molecularly Imprinted Solid Phase Extraction Pillar

WANG Yan-Hong1, HUO Jia-Ping1,2, ZHANG Hong1, WANG Shi-Cheng1,SI Shi-Hui2, LIN Gui-Feng1, LI Guo-Chen1, QI Wei11(Institute of Applied Ecology Chinese Academy of Sciences, Shenyang 110015)2(Institute of Chemistry and Chemical Engineering, Central South University, Changsha 410083)  
The molecular imprinted polymers(MIPs) was synthesized by polymerization for 17 h using atrazine as template, α-methacrylic aid(MAA) as monomer, ethylene glycol dimethacrylate(EDMA) as cross-linker and 2,2-azobisisobutyronitrile(AIBN) as initiator. This polymer could specially recognize atrazine. The polymers was grinded, sieved, washed and packed into cartridges. The adsorbability of the solid phase extraction(SPE) pillar being stuffed with the polymers was 600 times compared with that of the polymer sphere, and the extraction time of this SPE pillar was only 1/60 compared with that of polymer sphere, the recovery was 90% testing by HPLC. The SPE pillar could enrich atrazine at the concentration less than 2×10-8 mol/L in the water sample with the recovery of 89.3%. In comparison with C18 pillar, the MIPs-SPE pillar used only 1/3 time and 1/4 reagent, and got higher recovery, as well, purified the sample water more drastically, decreased the disturbance of peculiar peaks, improved the sensitivity and could protect the instrument against damage. And the water for agricultures could be tested using this method.
【Fund】: 中科院重要方向项目(No.KSCX2-YW-N-035);; 财政部专项绿色农业科学研究与示范项目(No.LSNY-2007-10);; 沈阳市大型仪器专项(No.2008GX-034)的资助
【CateGory Index】: X839.2
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2 LI Ling-ling(Chongqing Industry & Trade Polytechnic,Fuling 408000,China);Application of Molecularly Imprinted Polymers in Separation Science and Technology[J];Journal of Chongqing Industry & Trade Polytechnic;2011-01
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5 ZHANG Hong-Wu,GUO Jian-Wen,LI Kang,WANG Wei-Sheng, WU Yu-Ping,LU Qi-Wen,ZHAI Hai-Yun* (School of Pharmacy,Guangdong Pharmaceutical University,Guangzhou 510006,China);On-line Determination of Trimethoprim in Human Serum by Molecularly Imprinted Monolithic Column with Melamine Employed as Analogue Template[J];Chinese Journal of Analytical Chemistry;2012-05
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9 CHEN Kai-yin,LIU Jun-bo,CHENG Zhi-qiang,TANG Shan-shan College of Resources and Environment,Jilin Agricultural University,Changchun 130118,China;Preparation and characterization of Atrazine molecularly imprinted polymer microspheres[J];Journal of Lanzhou University(Natural Sciences);2012-01
10 WANG Zhong-dong~1,BAI Wen~1,WANG Yan-hong~2,WANG Shi-cheng~2,LIN Gui-feng~2 (1.College of Light Industry and Economics&Management,Jilin University,Changchun 130062,China; 2.Institute of Applied Ecology,Chinese Academy of Sciences,Shenyang 110015,China);Application of Molecular Imprinting Technology in Food Safety Detection and Analysis[J];Journal of Inner Mongolia University for Nationalities(Natural Sciences);2011-02
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2 Hu Shuguo Li Li He Xiwen **(State Key Laboratory of Functional Polymer Materials for Adsorption and Separat ion, Department of Chemistry, Nankai University, Tianjin 300071, China);Molecularly Imprinted Polymers: A New Kind of Sorbent with High Selectivity in Solid Phase Extraction[J];Progress In Chemistry;2005-03
3 SUN, Bao-Wei WU, Li-Qing LI, Yuan-Zong (Key Laboratory of Bioorganic and Molecular Engineering, Department of Chemical Biology, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871);Experimental and Theoretical Study on p-Hydroxybenzoic Acid Imprinted Polymers with Different Functional Monomers[J];Acta Chimica Sinica;2004-06
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7 AN Feng-kai1,2,PAN Hong-qing1,2,JIA Xiao-chuan1,2,WANG Shuo2 (1.Tianjin Entry-Exit Inspection and Quarantine Bureau,Tianjin 300457,China; 2. Key Laboratory of Food Nutrition and Safety,Ministry of Education,Tianjin University of Science and Technology,Tianjin 300457,China);APPLICATION OF MOLECULAR IMPRINTING TECHNOLOGY IN FOOD SAFETY DETECTION AND ANALYSIS[J];Food Research and Development;2009-03
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2 LI Lin et al (Department of Chemistry,Anshun College of Guizhou,Anshun,Guizhou 561000);Research Progress on the Residue Analysis of Triazole Pesticides[J];Journal of Anhui Agricultural Sciences;2008-22
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9 He Wei,Sun Shiqun,Zheng Haijun(School of Resources and Environmental Engineering,Hefei University of Technology,Hefei 230001,China);Research on Atrazine Detection Method in Surface Water[J];Environmental Science and Management;2012-04
10 WANG Hongying\ L Qiufeng\ CAO Shaokui (Department of Materials Engineering,Zhengzhou University,Zhengzhou,450052) SUN\ Hong (College of Chemistry and Chemical Engineering,Zhengzhou University,Zhengzhou,450052);Theophylline Recognition Copolymer Membranes Prepared by Molecular Imprinting Method[J];Acta Scicentiarum Naturalum Universitis Pekinesis;2001-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 WU Fang-hua(Fuzhou Product Quality Inspection,Fuzhou 350002,China);Study of New Technology on Solid Phase Extraction[J];Analysis and Testing Technology and Instruments;2012-02
2 LI Hui-Xiang1,XU Xiao-Li2,CHEN Hui1,ZHANG Song1,KONG Ji-Lie1 1(Department of Chemistry,Fudan University,Shanghai 200433,China)2(Shengsi Entry-Exit Inspection and Quarantine Bureau,Shengsi 202450,China);Fabrication of Molecularly Imprinted Electrochemical Sensor for Selective Detection of Propranolol Hydrochloride[J];Chinese Journal of Analytical Chemistry;2012-06
3 YANG Xiao1,2,ZHANG Zhao-Hui1,2,3,CHEN Xing2,ZHANG Ming-Lei2, LUO Li-Juan2,PENG Mi-Jun1,NIE Li-Hua3 1(Key Laboratory of Hunan Froest Products and Chemical Industry Engineering, Jishou University,Zhangjiajie 4270000,China) 2(College of Chemistry and Chemical Engineering,Jishou University,Jishou 41600,China) 3(State Key Laboratory of ChemoBiosensing and Chemometrics,Hunan University,Changsha 410082,China);Preparation of Bis(2-ethylhexyl) phthalate Imprinted Polymers Based on Multi-walled Carbon Nanotubes Surface and Its Application in Solid Phase Extraction[J];Chinese Journal of Analytical Chemistry;2012-06
4 QU Xue-yin1,2,3,WANG Jia-qi1,2,3,HAN Rong-wei1,2,3,XU Xiao-min1,2,3,ZHEN Yun-peng1,2,3, ZHENG Nan1,2,3,ZHAO Lian-sheng1(1.State Key Laboratory of Animal Nutrition,Institute of Animal Sciences, Chinese Academy of Agricultural Sciences,Beijing 100193,China; 2.Quality and Inspction Center of Milk and Milk Products(Beijing),Ministry of Agriculture,Beijing 100193,China; 3.College of Food Science and Engineering,Qingdao Agricultural University,Qingdao 266109,China);Main Risk Factor Analysis for Milk Quality and Safety Ⅴ.Hormones[J];China Animal Husbandry & Veterinary Medicine;2012-05
5 YIN Wei(Beijing Chemical Industrial Research Institute,Beijing 100022,China);Application of Modern Analytical Techniques in Detection of Food Additives[J];Journal of Beijing Technology and Business University(Natural Science Edition);2012-04
6 TAN Xiao-Wang1,SONG Yan-Xi1,WEI Rui-Ping2,YI Gu-Yang1 1(School of Environmental Science and Engineering,Donghua University,Shanghai 201620,China) 2(Shanghai Asia Pioneer Pharmaceutical Co.,Ltd,Shanghai 201203,China);Determination of Trace Bisphenol-A in Water Using Three-phase Hollow Fiber Liquid Phase Microextraction Coupled with High Performance Liquid Chromatography[J];Chinese Journal of Analytical Chemistry;2012-09
7 LIAO Tao1,WU Xiao-Cui1,2,WANG Shao-Hua1,XIE Song-Guang3,XIONG Guang-Quan1, GENG Sheng-Rong1,LI Xin1,ZU Xiao-Yan1,HU Xiao-Bo2 1(Hubei Engineering Research Center for Farm Products Irradiation,Institute for Farm Products Processing and Nuclear-Agricultural Technology,Hubei Academy of Agricultural Sciences,Wuhan 430064,China) 2(College of Food Science and Technology,Huazhong Agricultural University,Wuhan 430070,China) 3(Institute of Hydrobiology,Chinese Academy of Sciences,Wuhan 430072,China);Simultaneous Detection of Nine Kinds of Estrogens in Water by Solid Phase Extraction Coupled with Gas Chromatography-Mass Spectrometry[J];Chinese Journal of Analytical Chemistry;2013-03
8 Zhao Baobao,Hu Xiaoling,Li Ji(Department of Applied Chemistry,College of Science,Northwestern Polytechnical University,Xi'an 710072,China);Imprinting technique of biological molecule in aqueous phase[J];China Adhesives;2013-01
9 NONG Shu-Yu,LIN Fu-Hua,CHEN Lin-Li,HUANG Xiao-Jia,YUAN Dong-Xing(Key Laboratory of the Ministry of Education for Coastal and Wetland Ecosystem, College of the Environment and Ecology,Xiamen University,Xiamen 361005,China);Preparation of Stir Bar Sorptive Extraction Based on o-Nitrophenol Imprinted Polymer and Its Extraction Performance[J];Chinese Journal of Analytical Chemistry;2013-04
10 LONG Wei(School of Chemistry and Chemical Engineering,University of South China,Hengyang 421001,Hunan China);Quantization of Structures and Properties of Bisphenol A and Bisphenol B[J];Journal of Jishou University(Natural Sciences Edition);2012-04
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