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《Chinese Journal of Analytical Chemistry》 2011-07
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A Strategy for Constructing Sensitive and Renewable Molecular Imprinted Carbon Paste Sensor

CHEN Zhi-Qiang,LI Jian-Ping,LI Yu-Ping (College of Chemistry and Bioengineering,Guilin University of Technology,Guilin 541004)  
Oxytetracycline(OTC) molecular imprinted particles and carbon paste were mixed to prepare OTC molecular imprinted carbon paste sensor.The sensor could specifically recognize OTC and horseradish peroxidase(HRP) labeled OTC by the competition replacement reaction between them.The labeled HRP catalyzed the reaction between H2O2 and mediator hydroquinone,and the detection of OTC was based on the voltammetric monitoring of the electroreduction of the oxidized mediator,benzoquinone.A linear relationship between response current and logarithm of concentrations of OTC in the concentration range of 0.008-0.6μmol/L was obtained with a detection limit of 1.8 nmol/L.The sensor renewal was achieved by a simple mechanical polishing step of sensors′surface.The sensor is easy to prepare and use,low cost,high sensitivity and easy renewal.The sensor has been successfully applied to the determination of OTC in milk samples.The recoveries were 93.8%-96.6%.
【Key Words】： Molecular imprinted Oxytetracycline Electrochemical sensor Horseradish peroxidase Carbon paste
【Fund】： 国家自然科学基金(No.20665003);; 广西自然科学基金(No.0728214)资助
【CateGory Index】： O657.1;TP212.2
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6 ZHANG Hong-Cai,LIU Guo-Yan,SHANG Jing,WENG Zhi-Ying,CHAI Chun-Yan(School of Agricultrue & Biology,Shanghai Jiaotong University,Shanghai 200240);A Conductometric Sensor Based on Screen Printed Electrode Modified with Multi-walled Carbon Nanotubes and Molecularly Imprinted Membrane for Determination of Ractopamine in Pig Urine[J];Chinese Journal of Analytical Chemistry;2012-01
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3 SU Li-Qiang1,WANG Yuan1,HAN Shuang1,ZHANG Wei-Bing1,21(College of Chemistry and Chemical Enginering,Qiqihar University,Qiqihar 161006)2(East China University of Science and Technology,Shanghai 200237);Synthesis and Characterization of 2-(Methacryloylamino) ethyoxyl-2-methacrylate Ethandiol Ester Matrix Molecular Imprinting Chiral Separation Medium[J];Chinese Journal of Analytical Chemistry;2008-12
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