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《Journal of Analytical Science》 2012-05
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Spectroscopic Analysis of Molecular Recognition of Sudan Ⅰ Molecularly Imprinted Polymer

XU Xiao-yan,DENG Shi-jun,SUN Yuan-ming(Institute of Food Quality and Safety,South China Agricultural University,Key Laboratory of Food Quality and Safety of Guangdong Province,Guangzhou 510640)  
A molecularly imprinted polymer(MIP) with high selectivity was prepared by precipitated polymerization using Sudan redⅠ as template molecule,α-methacrylic acid(MAA) as functional monomer and ethylene glycol-methyl acrylate(EGDMA) as cross-linker.The adsorption property of the MIP was evaluated by equilibrium binding experiments,and the recognition mechanism of the MIP was also investigated by UV spectrum and 1H NMR.The results showed that the template molecule could interact with the functional monomer by cooperative hydrogen bonding.Infrared spectra further demonstrated the specific non-covalent hydrogen bonds between MIP and the template molecule.
【Key Words】： Sudan red Ⅰ Molecular imprinted polymer Molecular recognition
【Fund】： 广东高校优秀青年创新人才培育项目(No.209030)
【CateGory Index】： O631.3
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