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《Chinese Journal of Analysis Laboratory》 2011-03
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Application of parathion MIPs in solid-phase extraction

MA Chang,YANG Shu-ling,GAO Xiu-zhen,CHENG Zi-yu and ZHENG Hong (Qinghai Normal University,Xining 810008)  
A molecularly imprinted polymer was prepared by molecular imprinting technique using parathion as the template,epoxy resin as the monomer,diethylenetriamine as the curing agent and polyethylene glycol as the pore forming agent.The characteristics of selective separation and preconcentration of parathion and its structural analogs on the polymer were examined.Polymer was used to extract the parathion in the Napa Cabbage.The results indicated two different kinds of recognition sites in the MIP,and the MIP showed specific affinity toward parathion. Determination of parathion could be realized within 10 min by using C18 column with methanol-water(volume ratio of 70∶30) as mobile phase at a flow rate of 1.0 mL/min and 20 μL of injection volume at an absorption wavelength of 270 nm.
【Key Words】: Molecularly imprinted polymer Enrichment and separation Parathion
【Fund】: 教育部科学技术研究重点项目(208155);; 青海省科技厅项目(2008-G-166)资助
【CateGory Index】: O658.2
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