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《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 2000-03
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Studies of Selective Enrichment and Recognized Characteristics of Paracetamol Molecular Template Polymer

GUO Hong Sheng, HE Xi Wen , DENG Chang Hui, LI Yi Jun (Department of Chemstry, The Key Lab of Functional Polymer Materials for Adsorption and Separation, Nankai University, Tianjin 300071, China)  
A molecular templated synthetic polymer as the receptor highly selective for paracetamol was prepared by a molecular imprinting technique. The selective binding characteristics of the template polymer were evaluated by Scatchard analysis and Ultraviolet spectrometry. The results showed that the acrylamide as the functional monomer was more better than methacrylic acid for paracetamol selectivity, and a class of the same binding sites which could specially bind paracetamol by the interaction of hydrogen bonding were formed in the polymer and its dissociation constant was estimated to be 2 25×10 -3 mol/L. The selective binding experiment for substrates indicated that the polymer gave a higher affinity and selectivity for paracetamol. It is possible to be a good adsorption and binding material in the selective enrichment and determination of trace paracetamol in complex biosamples.
【Fund】: 国家自然科学基金!(批准号 :2 9775 0 11);; 南开大学吸附分离功能高分子材料国家重点实验室资助
【CateGory Index】: TQ460
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