Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《CHEMICAL RESEARCH IN CHINESE UNIVERSITIES》 2000-06
Add to Favorite Get Latest Update

Thermodynamic Study on Separation of Molecular Imprinting Chiral Stationary Phase

WANG Jin Fang, ZHOU Liang Mo , LIU Xue Liang, WANG Qing Hai, ZHU Dao Qian [WT5”BX](Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012, China) [WT5HZ]  
The effect of temperature on the chiral separation of the molecular imprinting polymer was investigated and the thermodynamic parameters were calculated. It was found that the chiral separation process was enthalpy controlled. Increasing the temperature decreases the capacity factor and chiral selectivity factor. The interactions between the analyte and the molecular imprinting chiral stationary phase were both non specific and specific, and only the difference of specific interaction results in the chiral separation. The imprinting cavities affected the thermodynamic parameters dramatically. The rebinding of the imprinted molecule into the imprinting cavities was favorable in view of energy and configuration because of their best compatibleness. [WT5HZ]
【Fund】: 国家自然科学基金! (批准号 :2 95 75 2 12 )
【CateGory Index】: O642
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 10 Hits
1 JIAO Feipeng HUANG Kelong YU Jingang PENG Xiahui ZHAO Xuehui NING Fengrong (College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Study on Process of Thermodynamics for Chiral Separation of Naproxen in Molecular Imprinting[J];Materials Review;2005-08
2 Liu Xueliang , Liu Ying, Wang Junde, Shang Zhenhua (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);The Application and Advancement of Molecular Imprinting Technology[J];Chinese Journal of Analytieal Chemistry;2002-10
3 SU Li Qiang 1, LIU Xue Liang 2 * , WANG Jun De 2, SHANG Zhen Hua 2 (1. School of Chemical Engineering, Qiqihaer University, Qiqihar 161006, China; 2. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012, China);Investigation of Separation of Caffeine and Theophylline on Molecular Imprinted Polymer Stationary Phases by High Performance Liquid Chromatography[J];Chemical Research In Chinese Universities;2001-07
4 SUN Xiao\|Hong\+\{1,2\}, LIU Yuan\|Fa\+3, GAO Sheng\|Li\+\{3*\}, ZHANG Xiao\|Yu\+3 (1. Chemical Research Institute of Northwest University, 2. Department of Chemical Engineering, 3. Department of Chemistry, Northwest University, Xi\+′an 710069, China;Research for the Thermochemical Properties of the Formation Reaction of -N-Phenyl-N′-(1,2,3-thiadiazol-5-yl)urea[J];Chemical Research In Chinese Universities;2002-03
5 SUN Ruifeng,YU Huimin,LUO Hui,SHEN Zhongyao (Institute of Biochemical Engineering, Department of Chemical Engineering, Tsinghua University, Beijing 100084);PREPARATION OF MOLECULARLY IMPRINTED POLYMERS AND STUDIES ON THEIR PORE STRUCTURE[J];Acta Polymerica Sinica;2005-02
6 JIANG Xu-hong1,2,TU Wei-ping1(1.Institute of Chemistry and Chemical Engineering of South China University of Technology,Guangzhou 510640,China;2.Department of Chemistry and Chemical Engineering of Zhongkai University of Agriculture and Technology,Guangzhou 510225,China);Progress in Thermodynamics,Physical Characterization and Modeling of Molecular Imprinting Polymers[J];Polymer Materials Science & Engineering;2009-03
7 ZHU Li,HU Xiao-ling(Department of Chemistry,Northwest Polytechnic University,Xi'an 710072,China);The progress on mechanism of molecular imprinted chiral recognition and applied in chromatography[J];China Adhesives;2007-10
8 ZHU Qiu-jin1,DAI Jun2,CHENShang-wei2,GU Xiao-hong2,TANG Jian2(1.School of Life Science,Guizhou University,Guiyang550025;2.Testing &Analysis Center,Southern Yangtze U-niversity,Wuxi 214036,Jiangsu);THERMODYNAMICS STUDY OF SEVERAL STEROLS ISOMERS SEPARATION ON TFMAA-co-TIRM MOLECULARLY IMPRINTED POLYMER[J];Guizhou Science;2007-S1
9 SHEN Gang-yi1,ZHANG Ai-qin2,YANG Xin-ling3 and LING Yun3(1.Key Laboratory of Chinese Minority Traditional Medicine,State Ethnic Affairs Commission and Ministry of Education of China,Minzu University of China,Beijing 100081;2.College of Life and Ennvironmental Science,Minzu University of China,Beijing 100081;3.Department of Applied Chemistry,China Agricultural University,Beijing 100094);Enantioseparation mechanism of several propanoic acid esters with α-substitute in capillary gas chromatography using cyclodextrin stationary phase[J];Chinese Journal of Analysis Laboratory;2013-03
10 Yuan Xiaoya,Yu Xianglin, Huang Jinxia (The Hubei Province Key Laboratory of Polymer Materials, Hubei University, Wuhan 430062, China);Molecularly imprinted polymer and its application in organic synthesis[J];Journal of Hubei University(Natural Science Edition);2002-03
【Citations】
Chinese Journal Full-text Database 4 Hits
1 Meng Zihui, Wang Qinghai, Zhu Daoqian, Zhou Liangmo (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Application of Molecular Imprinting in Chira1 Separation[J];Chinese Journal of Analytieal Chemistry;1997-03
2 Meng Zihui, Zhou Liangmo, Wang Jinfang, Wang Qinghai, Zhu Daoqian (Dalian Institute of Chemical Physics, Dalian ll60l2);Cmbined Interaction in Molecule Imprinting Chiral Stationary Phase[J];Chinese Journal of Analytieal Chemistry;1998-10
3 ZHOU Jie, HE Xi Wen *, YANG Wan Long, SHI Hui Ming (Department of Chemistry, Nankai University, Tianjin, 300071);Studies on Character of Adsorption and Recognition of Etharidine Template Polymer[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-09
4 WANG Jin - Fang ZHOU Liang - Mo MENG Zi - Hui WANG Qing - Hai ZHU Dao - Qian ( Dalian Institute of Chemical Physics , The Chinese Academy of Sciences , Dalian, 116012 ) ( The People' s Liberation Army Academic of Military Medicine Sciences , Beijing, 100850 );Highly Efficient Molecule Imprinting Chiral Stationary Phase Utilizing Combined Basic Functional Monomers[J];Acta Chimica Sinica;1999-10
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 YOU Jing CHEN Shulian WANG Guojun LU Haojie (Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences Lanzhou 730000);Molecular Imprinting Technique[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;1999-04
2 Liu Qin, Zhou Yongxin , Liu Yintang (Beijing Institute of Pharmacology and Toxicology, Beijing 100850);Recent Progresses in Research on Molecular Imprinting Sensors[J];Chinese Journal of Analytical Chemistry;1999-11
3 Wang Jiniang , Zhou liangmo , Meng Zihui , Liu Xueliang , Wang Qinghai , Zhu Daoqian(Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012)(Academic of Military Medicine Sciences , Beijing 100850);Effect of Rigidity of the Imprinted Molecule to Chiral Separation of Molecular Imprinting Chiral Stationary Phase[J];Chinese Journal of Analytical Chemistry;1999-12
4 Meng Zihui; Zhou Yongxin; Feng Jianlin;Liu Yintang; Yun Liuhong; Ruan Jinxiu(Beijing Institute of Pharmacology and Toxicology, Beijing 100850);The Research of Adsorption of Organophosphorus Toxicants on Molecule Imprinting Polymers[J];CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY;2000-04
5 Meng Zihui. (Institute of Pharmacology and Toxicology, Academy of Military Medical Sciences, Beijing 100850) Zhou Liangmo, Wang Jinfang, Wang Qinghai, Zhu Daoqian (Dalian Institute of Chemical and Physics, Chinese Academy of Sciences, Dalian 116012);The Structure Characterization for Molecule Imprinting polymers and the Thermodynamic Study in the Chiral Separation Process[J];CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY;2000-08
6 Wang Jinfang, Zhou Liangmo,Liu Xueliang,Wang Junde, Shang Zhenhua (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Simultaneous Chiral Separation of Two Pairs of Enantiomers Using Series Column of Molecular Imprinted Phase[J];Chinese Journal of Analytieal Chemistry;2000-09
7 Guo Hongsheng, He Xiwen (Department of Chemistry, Nankai University, Tianjin 300071);A Study on the Binding Characteristics of Molecular Imprinted Polymer Selective for Cefalexin in Aqueous Media[J];CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY;2000-10
8 Wang Jinfang,Zhou Liangmo, Liu Xueliang,Wang Qinghai,Zhu Daoqian (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Tribasic Cross-linker Molecular Imprinted Chiral Stationary Phase[J];CHINESE JOURNAL OF ANALYTIEAL CHEMISTRY;2000-10
9 Wang Jinfang, Liu Xueliang, Wang Junde, Shang Zhenhua, Yu Yinian (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Simultaneously Molecular Imprinting Chiral Stationary Phase[J];Chinese Journal of Analytieal Chemistry;2000-12
10 Ying Tailin ,Gao Mengjiao,Zhang Xiaolan (Deptartment of Environmental Science and Engineering,Shanghai University,Shanghai 200072);Highly Selective Technique-Molecular Imprinting[J];Chinese Journal of Analytieal Chemistry;2001-01
China Proceedings of conference Full-text Database 1 Hits
1 BING Naici,XU Zhenliang,YANG Zuoguo (Chemical Engineering Research Center,ECUST,Shanghai 200237,China);Preparation and application of molecularly imprinted membrane(MIM)[A];[C];2005
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 YANG Ping,SUN Yi-min(College of Chemistry and Materials Science,Anhui Normal University,Wuhu 241000,China);Method of Molecular Dynamics Simulation and Its Application[J];Journal of Anhui Normal University(Natural Science);2009-01
2 GAO Da-xiang,LI Zhao-lan,JIAO Qing-cai,GUO Li-yun (College of Life Science, Nanjing University, Nanjing 210093, China);Study on Resolution of DL-Alanine by Aminoacylase from Cunnighamella echinulata[J];Amino Acids & Biotic Resources;2005-02
3 WEI Yaoguang, ZHENG Deling, FU Dongmei, ZHOU Ting Information Engineering School, University of Science and Technology Beijing, Beijing 100083, China;Artificial immune algorithm based on biological immune clone selection and immune network theory[J];Journal of University of Science and Technology Beijing;2005-02
4 DAI Rong-ji,SU Cai-lian,WU Hai-yan,DENG Yu-lin(School of Life Science and Technology,Beijing Institute of Technology,Beijing 100081,China);Separation of Salsolinol Using β-Cyclodextrin-Modified Chiral Membrane[J];Transactions of Beijing Institute of Technology;2008-06
5 ZHENG Ximing~(12) TU Weiping~1 (1 Institute of Chemical Engineering of SCUT. Guangzhou 510640; 2 Department of Chemistry and Environment Engineering, Nanping Teachers College, Nanping 353000);Influential Factors of Capabilities of Combination and Recognition in Molecularly Imprinted Polymers[J];Materials Review;2004-10
6 JIAO Feipeng HUANG Kelong YU Jingang PENG Xiahui ZHAO Xuehui NING Fengrong (College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Study on Process of Thermodynamics for Chiral Separation of Naproxen in Molecular Imprinting[J];Materials Review;2005-08
7 Li Ping Rong Fei Xie Yibing Zhu Xinle Yuan Chunwei ( 1Department of Biomedical Science and Medical Engineering, Southeast University, Nanjing 210096, China) ( 2Department of Bioengineering, Beijing University of Aeronautics and Astronautics, Beijng 100083, China);Study on binding characteristics of (S)-naproxen imprinted polymer and performance of its complexes during preparation[J];Journal of Southeast University (Natural Science Edition);2003-04
8 Zhou Yingzhen~1 Shan Wenzhi~2 Wang Xingyong~1 (1 School of Chemical Engineering and Technology,China University of Mining and Technology; 2 college of life science and pharmaceutical engineering,Nanjing university of technology,Xuzhou,Jiangsu 221007,China);Brush—type chiral stationary phase and its application in chiral resolution[J];Fujian Analysis & Testing;2007-03
9 YOU Jing CHEN Shulian WANG Guojun LU Haojie (Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences Lanzhou 730000);Molecular Imprinting Technique[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;1999-04
10 Zhou Zhiqiang\ Zhang Hongyan\ Yu Zhaowen\ Hou Jingguo\ Chen Liren(Lanzhou Institute of Chemical Physics, the Chinese Academy of Sciences Lanzhou 730000);Enantiomeric Resolution of Chiral Drugs by HPLC[J];ANALYSIS AND TESTING TECHNOLOGY AND INSTRUMENTS;1998-01
China Proceedings of conference Full-text Database 1 Hits
1 LU Rong,WAN Ren-zhong,FAN Hui-rong,LIU Chang-xiao 1 Tianjin State Key Laboratory of Pharmacokinetics and Pharmacodynamics,Tianjin Institute of Pharmaceutical Research,Tianjin 300193,China; 2 Shenyang Pharmaceutical University,Shenyang 110016,Liaoning,China;Pharmacokinetic study of NBP optically active isomers based on chiral resolution technology with chiral stationary phase[A];[C];2009
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 HU Jian-hua et al(Research center of Environmental Science,Zhejiang Univeristy of Technology,Hangzhou,Zhejiang 310032);Enantiomeric Separation of O,O-dimethyl-1-(4-methyloxyphenoxy-acetoxy) ethylphosphonate by High Performance Liquid Chromatography[J];Journal of Anhui Agricultural Sciences;2007-23
2 HONG Yuan-xin et al (Institute of Liberal and Science,Tarum University,Alaer,Xinjiang 843300);Molecular Imprining Technologies for Natural Product Research Active Ingredients Progress[J];Journal of Anhui Agricultural Sciences;2008-21
3 ZHANG Qiaozhen SHI Jinsheng DENG Qiliang JING Zuoliang (Institute of Science,Tianjin University of Science and Technology,Tianjin 300222);Molecular Imprinting Polymer[J];Materials Review;2003-S1
4 JIAO Feipeng HUANG Kelong YU Jingang PENG Xiahui ZHAO Xuehui NING Fengrong (College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Study on Process of Thermodynamics for Chiral Separation of Naproxen in Molecular Imprinting[J];Materials Review;2005-08
5 LI Hailong,WANG Sui,GUO Zhiyong,WANG Meili,CHEN Danfeng,WEI Danyi (State Key Laboratory Base of Novel Functional Materials and Preparation Science,Faculty of Materials Science and Chemical Engineering,Ningbo University,Ningbo 315211);Applications of Molecular Imprinted Monolithic Material in Solid-phase Extraction and Its Prospect[J];Materials Review;2008-S3
6 Liu Ying, Liu Xueliang, Wang Junde  (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);The Adsorption Property of Nicotine-Imprinted Polymer[J];Chinese Journal of Analytical Chemistry;2003-10
7 Zhang Jing, He Langchong *, Fu Qiang (College of Medicine, Xi′an Jiaotong University, Xi′an 710061);Preparation of Strychnine Molecularly Imprinted Monolithic Column[J];Chinese Journal of Analytical Chemistry;2005-01
8 FU Ruo nong (Department of Chemistry, Beijing Institute of Technology, Beijing 100088),Fenxi Shiyanshi,2003,22(2):94~107;Advances on gas chromatography in China[J];Analytical Laboratory;2003-02
9 YAN Liu\|Shui, WANG Yi\|Ming, WANG Zong\|Hua, LUO Guo\|An  (Department of Chemistry, Tsinghua University, Beijing 100084, China );Molecularly Imprinted Polymer Monoliths Prepared in Capillaries by Photoinitiated in situ Polymerization for the Screening of Caffeine[J];Chemical Research In Chinese Universities;2001-12
10 WANG Hong, HUANG Liang, SUN Yan (Department of Biochemical Engineering, School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072);PREPARATION AND CHARACTERIZATION OF THEOPHYLLINE CRYSTAL-IMPRINTED POLYMERS[J];Acta Polymerica Sinica;2004-02
China Proceedings of conference Full-text Database 5 Hits
1 Zhu Qiujin,~aWang Liping~b,WU Shengfang~b,Joseph Wasswa~c Gu Xiaohong~b,Tang Jian~(b,c) a School of Life Sdence,Guizhou University,Cuiyang,550025,China b State Key Laboratory ofFood Science and Technology,Jiangnan University,Wuxi 214122,China c School of Food Science Jiangnan University,Wuxi 214122,China;Selectivity of molecularly imprinted solid phase extraction for sterol compounds[A];[C];2010
2 ZHANG,Yu-Ping ZHANG,Xiao-Yan SONG,Bao-An~* (State Key Laboratory Breeding Base of Green Pesticide and Agricultural Bioengineering,Key Laboratory of Green Pesticide and Agriculture Bioengineering,Ministry of Education,Center for Research and Development of Fine Chemicals,Guizhou University,Guiyang 550025,China);Enantioseparation and Study of Thermodynamical Property of Quinazoline Derivatives Bearing α-Aminophosphonate Moiety by HPLC[A];[C];2010
3 LIU,Guo-Qing KANG,Shan-Shan XIANG,Cui YAO,Bi-Xia WENG,Wen~* (Department of Chemistry and Environmental Science,Zhangzhou Normal University,Zhangzhou,363000);Reversal of elution order between enantiomers of binaphthol onChiralpak IA chiral column[A];[C];2010
4 XIANG,Cui KANG,Shan-Shan LIU,Guo-Qing YAO,Bi-Xia WENG,Wen~* (Department of Chemistry and Environmental Science,Zhangzhou Normal University,Zhangzhou,363000);Reversal of elution order between enantiomers of naproxen On Chiralpak IA column[A];[C];2010
5 ZHAN,Feng-Ping LIANG,Ting HUANG,Bei YAO,Bi-Xia WENG,Wen~* (Department of Chemistry and Environmental Science,Zhangzhou Normal University,Zhangzhou,363000);Reversal of elution order between enantiomers of binaphthol on Chiralcel OD-H column[A];[C];2010
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved