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《Polymer Materials Science & Engineering》 2009-03
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Progress in Thermodynamics,Physical Characterization and Modeling of Molecular Imprinting Polymers

JIANG Xu-hong1,2,TU Wei-ping1(1.Institute of Chemistry and Chemical Engineering of South China University of Technology,Guangzhou 510640,China;2.Department of Chemistry and Chemical Engineering of Zhongkai University of Agriculture and Technology,Guangzhou 510225,China)  
Molecularly imprinted polymers(MIPs) are polymers that can be tailored with affinity and selectivity for a molecule of interest.In addition to improving binding performance of MIPs and finding more efficient synthetic methodologies,thermodynamic aspects,including modeling,analytical and numerical methods used for calculating the adsorption isotherms and the adsorption energy distribution were important research topics in recent years.Progress in the thermodynamics,physical characterization and modeling of molecular imprinting was reviewed according the stage of preparation of the MIPs: the formation of pre-polymerization complex,the construction of polymer network and the binding properties of MIPs.
【Fund】: 广东省自然科学基金资助项目(04020123)
【CateGory Index】: O631.3
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