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《高分子科学(英文版)》 2016-01
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Effects of Functionalized Graphenes on the Isothermal Crystallization of Poly(L-lactide) Nanocomposites

Li-fen Zhao;Qi Li;Ru-liang Zhang;Xiu-juan Tian;Lei Liu;School of Materials Science and Engineering, Shandong University of Science and Technology;  
The effects of graphene oxide(GO) with polar groups and functionalized GO(f GO) with nonpolar groups on the isothermal crystallization of poly(L-lactide)(PLLA) were compared. Functionalized GO was obtained by grafting octadecylamine and characterized by FTIR, WAXD and TGA. Isothermal crystallization kinetics of PLLA/GO and PLLA/f GO nanocomposites were investigated by combining DSC data and Avrami equation. The results showed that f GO could improve PLLA crystallization rate more obviously than GO. By analyzing the morphology obtained from POM, SEM and TEM, it was found f GO with large layer space dispersed better in PLLA and supplied more nucleation sites than GO. Therefore, for the multilayer graphene, increasing the layer spaces is important to improve its dispersion in polymers, which will cause the crystal kinetics changing of polymers.
【Fund】: financially supported by the National Natural Science Foundation of China(Nos.51503117 and 51403119);; Promotive Research Fund for Excellent Young and Middle-aged Scientisits of Shandong Province(No.BS2013CL032)
【CateGory Index】: TB33
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