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《高分子科学(英文版)》 2018-02
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Salen-iron Complexes: Synthesis, Characterization and Their Reactivity with Lactide

Yuan Liang;Ran-Long Duan;Chen-Yang Hu;Li-Li Li;Xuan Pang;Wan-Xi Zhang;Xue-Si Chen;Department of Materials Science and Engineering, Jilin University;Key Laboratory of Polymer Ecomaterials, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences;  
Schiff-base metal complexes as efficient catalysts are widely used in ring-opening polymerization of cycle esters. The salen Fe complexes were formed with their excellent biocompatibility and less toxicity. A series of salen Fe complexes were designed in this work in order to study the activity and control of polymerization of lactide. The salen Fe complexes' activities changed with the ligands configuration and substituent groups.
【Fund】: financially supported by the National Natural Science Foundation of China (Nos. 21574124 and 51503203)
【CateGory Index】: O633.14;O643.36
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