Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《高分子科学(英文版)》 2018-10
Add to Favorite Get Latest Update

Initiation, Development and Stabilization of Cavities during Tensile Deformation of Semicrystalline Polymers

Ying Lu;Yong-Feng Men;State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences;University of Science and Technology of China;  
By using polybutene-1 as a typical example, we illustrate the initiation, development and stabilization of cavities in the sample during tensile deformation. Samples with the same crystallinity, long spacing and crystalline lamellar thickness but very different sizes of spherulites were prepared via changing the melt history. Dimension of cavities during stretching the samples was determined by in situ ultra small angle X-ray scattering techniques. It turned out that the size of the cavities was bigger in the sample with larger spherulites than the one with smaller spherulites. The results show clear evidence of initiating cavities within crystalline phase at the grain-boundary of crystalline blocks, growing of cavities passing through parallel stacked lamellar crystals and amorphous layers and finally stablized by tilted lamellae at both ends of the plate-like cavities within the spherulites.
【Fund】: financially supported by the National Natural Science Foundation of China(Nos.51525305 and 21134006);; the Newton Advanced Fellowship of Royal Society(No.NA150222)
【CateGory Index】: O73;O631
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved