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《Journal of Functional Materials》 2012-06
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Preparation and evaluation of berberine-Cl imprinted polymers by using silica-gel as sacrificed materials

LI Hui1,LI Yu-zhuo1,LI Zhi-ping2,LI Ya-nan1,PENG Xi-yang1(1.Key Laboratory of Plant Resource Conservation and Utilization of College of Hunan Province, Jishou University,Jishou 416000,China; 2.College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000,China)  
Berberine-Cl imprinted polymer was synthesized on silica-gel particle as a sacrificed material by using berberine-Cl as template,MAA or 4-VP,EDMA and AIBN as function monomer,cross-linker and initiator,respectively.Polymer particle size was observed by optical microscope and its rebinding behavior to template investigated by IR spectrum and static adsorption of berberine-Cl on polymers.Results indicated a higher rebinding ability of Mip prepared by using MAA as functional monomer than by using 4-VP.This selective rebinding of template on the Mip resulted from specific affinity sites complementary to template in size,shape and functional group.Also,dissociation constants and maximum adsorption amount of two types of adsorption sites on Mip were obtained by Scatchard analysis.
【Key Words】: molecular imprinting technique berberine-Cl silica-gel as sacrificial materials molecularly imprinted polymer recombination
【Fund】: 国家自然科学基金资助项目(21077042)
【CateGory Index】: O631.3
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