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《Journal of Functional Polymers》 1988-01
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Degradation Kinetics on Photocrosslinking Products of Cyclized Rubber and Solubitizing Mechanism of Dodecyl Benzene Sulfonic Acid

Huang Junlian, Wu Qingfeng (Institute of Material Science, Fudan univ., shanghai)  
The dynamic behaviors of degradation reaction on photocrosslinking products of photosensitive polymer as cyctized rubber were studied. The order and activation energy of degradation reaction were determined under the influences of alkyl benzene sulfonic acids with different alkyl group. The effects of the length of alkyl group and the conc. of alkyl benzene sulfonic acids on rate of degradation reaction were discussed. The degradation reaction rate by using dodecyl benzene sulfonic acid is the highest among the used alkyl benzene sulfonic acids. The solubilizing mechanism was suggested.
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