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《Journal of Functional Polymers》 2008-04
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"Living" Radical Polymerization of Methyl Methacrylate Using CuBr as Catalyst in [Hmim][CH_3COO]

WU Lian-bin1,HU Zi-qiang1,LAI Guo-qiao1,WU Ji-rong1,SUN Wei-lin2(1.Key Laboratory of Organosilicon Chemistry and Material Technology of Education Ministry,Hangzhou Normal University,Hangzhou 310012,China;2.Department of Polymer Science and Engineering,Zhejiang University,Hangzhou 310012,China)  
"Living" radical polymerization of methyl methacrylate was investigated in a new reaction system.Ethyl 2-bromoisobutyrate/CuBr/[Hmim][CH_3COO]/MMA,in which [Hmim][CH_3COO] ionic liquid is a good solvent to CuBr.The polymerization belongs to an ATRP process.The effect of initiator concentration on the polymerization was examined.With the increasing of the concentration of initiator,the efficiency of initiation decreases.The polymerization is well controlled and exhibited living characteristics at 50 ℃.PMMA obtained by this procedure are narrow disposed.PDI is less than 1.26.
【Fund】: 浙江省人才基金(R203154);; 浙江省自然基金(Y405124);; 浙江省教育厅项目(20050721)
【CateGory Index】: O631.5
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【Citations】
Chinese Journal Full-text Database 1 Hits
1 Wang Xiaosong Luo Ning Ying Shengkang(Lab. of Living Polymerization, East China University of Science and Technology, Shanghai 200237);Living Radical Polymerization of MMA Promoted by EPN-Br / CuX / bpy[J];JOURNAL OF FUNCTIONAL POLYMERS;1998-01
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LIU Yan-Fei, WAN Xiao-Long, YING Sheng-Kang~ (Laboratory of Living Polymerization, East China University of Science and Technology, Shanghai 200237, China);Studies on Synthesis of P(S-b-Me-OXZ) Block Copolymers[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;2000-07
2 GUO Jianhua, LUO Xianan, WU Pingping, HAN Zhewen (Department of Polymer Science and Engineering,East China University of Science and Technology,Shanghai\ 200237);A CATALYTIC SYSTEM INCLUDING Al(OiPr)\-3 AS A PROMOTER FOR ATOM TRANSFER RADICAL POLYMERIZATION[J];ACTA POLYMERICA SINICA;1999-06
3 YUAN Jinying 1,2 , WEI Gaoyuan 1, WANG Yanmei 2, PAN Caiyuan 2 ( 1 Department of Polymer Science and Engineering, Peking Unviersity, Beijing\ 100871) ( 2 Department of Polymer Science and Engineering, University of Science and Technolog;SYNTHESES AND CHARACTERIZATION OF ABA TYPE AMPHIPHILIC BLOCK COPOLYMERS[J];Acta Polymerica Sinica;2001-05
4 YUAN Jin-ying (Department of Polymer Science and Engineering, Beijing University, Beijing 100871, China) WANG Yan mei, PAN Cai yuan (Department of Polymer Sicence and Engineering, University of Science and Technology of China, Hefei 230026, China);SYNTHESIS OF ABA TYPE BLOCK COPOLYMERS BY ATOM TRANSFER RADICAL POLYMERIZATION[J];Polymeric Materials Science & Cngineering;2002-05
5 LI Yu ting 1, ZHANG Wei 2, ZHANG Min 2, ZHANG Yan 2, WANG Jin shan 2, HUANG Jia xian 2 (1.Teda Bio Tech. Company, Tianjin 300457, China; 2.Department of Chemistry, Nankai University, Tianjin 300071, China);THE POLYMERIZATION OF 2-[(TRIFLUOROACETYL) OXY]ETHYL METHACRYLATE[J];Polymeric Materials Science & Engineering;2003-03
6 WANG Tao 1, ZHANG Zhao bin 1, LUO Ning 1, YING Sheng kang 1, LIU Qing 2 (1. Laboratory of Living Polymerization, ECUST, Shanghai 200237, China) (2. Research Institute of Beijing Yanshan Petrochemical Corporation, Beijing 102549, China);“Living” Radical Copolymerization of Styrene and Methyl Methacrylate Promoted by Eib-Br/CuBr/bpy[J];JOURNAL OF FUNCTIONAL POLYMERS;2000-02
7 YUAN Jin ying 1,2 , WANG Yan mei 2,, PAN Cai yuan 2 (1. Department of Polymer Science and Engineering, Peking University, Beijing 100871, China; 2. Department of Polymer Science and Engineering, University of Science and Technology of China,;Effect of the Structures of Initiators on the Atom Transfer Radical Polymerization of Styrene[J];Journal of Functional Polymers;2001-01
8 WANG Mei,LIN Wen-jing,HUANG Hai-liang,ZHANG Si(Faculty of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China);Advance in ATRP and Synthesize Block Copolymers by ATRP[J];Technology & Development of Chemical Industry;2010-09
9 HAN Su-yu, ZHU Xue-wang, ZHANG Yan,WANG Yan-hong, WANG Jing-hui,LUO Qing-zhi,WANG De-song (College of Sciences, Hebei University of Science and Technology, Shijiazhuang 050018,China);Progress of Atom Transfer Radical Polymerization[J];Hebei Chemical Engineering and Industry;2006-08
10 XIA Pan-deng~1 , GENG Bing~1 , LU Cui-ping~2 , XU An-hou~1 , CHU Shan-zhuang~1 , ZHANG Shu-xiang~1 (1.College of Chemistry and Chemical Engineering , Ji′nan University , Ji′nan 250022 , China ; 2. Ji′nan Huaiyin District Real Estate Development Company , Ji′nan 250021 , China );Research Progress of Polymerization of Atomic Transfer Free Radical[J];Henan Chemical Industry;2005-04
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