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《Journal of Functional Polymers》 2008-04
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Studies on Confined Crystallization of Polymers

ZHANG Feng-bo,YU Pei-qian,XIE Xu-ming(State Key Laboratory of Advanced Materials,Institue of Polymer Science and Engineering,Department of Chemical Engineering,Tsinghua University,Beijing 100084,China)  
Nowadays,great attention has been paid to confined crystallization of polymers under specific environment due to their wide applications in the field of nano materials,such as miniaturized components and nano-patterned templates.The progress in the study on confined crystallization of polymers is reviewed in this paper.For thin and ultra-thin films of homopolymers and random copolymers,the confined crystallization is widely studied on the basis of geometry effect and interfacial effect,which become dominant while the film thickness is reduced.As for block copolymers,with unique nanophase separation structure,the confined crystallization in the bulk is due to the competition between vitrification of amorphous block and crystallization of crystalline block,and the spatial effect and chain end effect,and the latter one may play a more important role.
【Fund】: 国家自然科学基金(2067404420874056)资助项目
【CateGory Index】: O631.2
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【Citations】
Chinese Journal Full-text Database 3 Hits
1 WANG Zhen, KONG Xiang-Ming, GAO Feng, HU Ping, XIE Xu-Ming * (Polymer Istitute, Department of Chemical Engineering, Advanced Materials Laboratory of Materials Research Center of Educational Ministry, Tsinghua University, Beijing 100084, China);The Effect of Polymer Film Thickness on the Polymer Crystallization Restricted on Substrate[J];Chemical Research In Chinese Universities;2003-03
2 WANG Zhen1, XU Jun1, XIE Xu-Ming 1*, WANG Xiu-Feng2 (1. Insistite of Polymer Science and Engineering, Department of Chemical Engineering; 2. Department of Physics, Tsinghua University, Beijing 100084, China);AFM Observation of Sunflower-like Crystalline Morphology Formed in Ultra-thin Film of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)[J];Chemical Research In Chinese Universities;2005-01
3 WANG Zhen~1,XIE Xu-Ming~1*,YANG Rui~1,WANG Xiu-Feng~2 (1.Institute of Polymers,Department of Chemical Engineering,2.Department of Physics,Tsinghua University,Beijing 100084,China);Crystalline Morphologies and Molecular Orientation of Poly(ε-caprolactone) Thin Films[J];Chemical Journal of Chinese Universities;2006-01
【Co-citations】
Chinese Journal Full-text Database 7 Hits
1 CHEN Zhou, WANG Zhen, YANG Rui, XIE Xu-Ming * (Institute of Polymer Department of Chemical Engineering, Advanced Materials Laboratory of Materials Research Center of Education Ministry, Tsinghua University, Beijing 100084, China);IR Studies on Conformation Changes of Poly(ethylene oxide) Thin Films[J];Chemical Research In Chinese Universities;2004-02
2 WANG Zhen1, XU Jun1, XIE Xu-Ming 1*, WANG Xiu-Feng2 (1. Insistite of Polymer Science and Engineering, Department of Chemical Engineering; 2. Department of Physics, Tsinghua University, Beijing 100084, China);AFM Observation of Sunflower-like Crystalline Morphology Formed in Ultra-thin Film of Poly(3-hydroxybutyrate-co-3-hydroxyhexanoate)[J];Chemical Research In Chinese Universities;2005-01
3 WANG Zhen~1,XIE Xu-Ming~1*,YANG Rui~1,WANG Xiu-Feng~2 (1.Institute of Polymers,Department of Chemical Engineering,2.Department of Physics,Tsinghua University,Beijing 100084,China);Crystalline Morphologies and Molecular Orientation of Poly(ε-caprolactone) Thin Films[J];Chemical Journal of Chinese Universities;2006-01
4 MENG Yan-Feng~(1,2,3),WEN Hui-Ying~1,LI Hong-Fei~1,TANG Yu-Jing~1,MEN Yong-Feng~1,JIANG Shi-Chun~(1*),AN Li-Jia~1,(1.State Key Laboratory of Polymer Physics and Chemistry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China;2.School of Chemistry & Material,Ludong University,Yantai 264025,China;3.Graduate School of the Chinese Academy of Sciences,Beijing 100049,China);Investigation on Isothermal and Non-isothermal Crystallization Kinetics of Poly(ε-caprolactone)[J];Chemical Journal of Chinese Universities;2006-11
5 KONG Xiangming, HE Shugang, WANG Zhen, CHEN Zhou, XIE Xuming (Department of Chemical Engineering, Materials Research Center, Tsinghua University, Beijing 100084);THE STUDY ON THE CRYSTAL MORPHOLOGY OF PCL THIN FILMS BY AFM[J];Acta Polymerica Sinica;2003-04
6 WANG, Bi-Qin JIAN, Zhong-Bao ZHAO, Ke-Qing YU, Wen-Hao HU, Ping (College of Chemistry and Material Sciences, Sichuan Normal University, Chengdu 610066);Synthesis and Mesomorphism of Unsymmetrical Liquid Crystalline Dimers with Imine and Cholesteryl Moieties[J];Acta Chimica Sinica;2007-22
7 CUI Guang-jun~1 WANG Yang~1 LI Hai-dong~(1,2)(1.Chemical Engineering Department,Changchun University of Technology,Changchun 130012,China;2.State Key Laboratory of Polymer Physics and Chemisry,Changchun Institute of Applied Chemistry,Chinese Academy of Sciences,Changchun 130022,China);Nonisothermal Crystallization Behavior of Poly(s-caprolatone)[J];China Plastics;2008-11
【Secondary Citations】
Chinese Journal Full-text Database 6 Hits
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