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《Materials for Mechanical Engineering》 2015-09
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Thermal Degradation Kinetics of Pure PVC and CaCO_3/PVC Composites

LIU Hai;WANG Jie;WEN Sheng;GONG Chun-li;ZHENG Gen-wen;XIONG Chuan-xi;Faculty of Chemistry and Material Science,Hubei Engineering University;School of Materials Science and Engineering,Wuhan University of Technology;  
Nano-CaCO3 particles were firstly modified using liquid polymer modifier,and then were used to prepare CaCO3/PVC composites by melt blending.The thermal degradation kinetics of pure PVC and its composites were discussed using Friedman method and Kissinger method.The results show that the degradation mechanism of pure PVC and its composites were consistent at the first stage of degradation,and their thermal degradation were both temperature and time dependent.The thermal degradation rate of PVC material was changed only by adding modified CaCO3 particles,but thermal degradation mechanism was not changed.
【Fund】: 湖北省教育厅科学技术研究计划青年人才项目(Q20142702)
【CateGory Index】: TQ325.3;TB332
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