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《Journal of Guangxi Normal University(Natural Science Edition)》 2007-01
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Synthesis and Crystal Structure of [Mn(phen)_3](ClO_4)_2·CH_3OH

ZHANG Yun-liang,ZHANG Zhi-li,HUANG Yao,TAN Ming-xiong,CHEN Zhen-feng(College of Chemistry and Chemical Engineering,Guangxi Normal University,Guilin 541004,China)  
The title complex [Mn(phen)3](ClO4)2·CH3OH was synthesized and characterized by elemental analysis and IR spectrum.The results of X-ray single-crystal diffraction analysis of the title complex show that the crystal crystallize in triclinic system,space group P-1 with formula C37H37Cl2MnN6O9,cell parameters:a=1.12999(7),b=1.28361(8),c=1.44948(9) nm,α=85.385(1) °,β=76.134(1) °,γ=69.890(1) °,Mr=834.9,Z=4.In the title complex,the metal center Mn(Ⅱ) ion is six-coordinated by three 1,10-phen ligands and formed a distorted octahedron geometry,and the stable three-dimensional networks are formed via π-π stacking and hydrogen bonding interactions.
【Fund】: 国家自然科学基金资助项目(20361002);; 教育部新世纪优秀人才支持计划资助项目(NCET-04-836);; 广西科技计划应用基础研究专项经费资助项目(0575046);; 广西“新世纪十百千人才工程”资助项目(2003223)
【CateGory Index】: O641.4
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