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《ACTA OPTICA SINICA》 1999-01
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Spectrum and Structure of Eu 3+ ∶Y 2SiO 5 Crystal

Xie Liming Chen Lingbing Xue Shaolin Zhao Youyuan Li Fuming (Department of Physics, Fudan University, Shanghai 200433) Zhang Shoudu Wang Haobing (Shanghai Institute of Optics and Fine Mechanics, The Chinese Academy of Sciences, Shangha  
Narrow line fluorescence spectra of Eu 3+ ∶Y 2SiO 5 crystal are obtained by exciting with Ar + laser at 514.5 nm, 488 nm and He Cd laser at 441.6 nm. Complex spectral structure is analyzed and identified, which is understood as originating from taking off the energy level degeneracy of Eu 3+ in the host crystal field and the possession of two inequivalent lattice sites of Eu 3+ in the host crystal. X ray powder diffraction pattern of Eu 3+ ∶Y 2SiO 5 shows that the the crystal is monoclinic. The lattice constants a, b, c and β are obtained by a simulation with the measured difraction angles, and found that the lattice constants a, b, c are slightly larger but very close to those of undoped Y 2SiO 5 crystal.
【Fund】: 国家自然科学基金
【CateGory Index】: O734,O731
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