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《Industrial Catalysis》 2003-12
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Synthesis and characterization of methane sulfonates and their catalytic activities for esterification

WANG Min, JIANG Heng, GONG Hong, WANG Rui (Institute of Petrochemical Engineering, Liaoning University of Petroleum & Chemical Technology, Liaoning Fushun 113001, China)  
Methane sulfonates of magnesium, aluminum, calcium, ferrous iron, cobalt, nickel, copper, zinc, barium, lanthanide, cerous cerium, praseodymium and neodymium were synthesized and characterized by TGA and FTIR. Catalytic activity of the methanesulfonates was studied and compared with other Lewis acids under the following condition : n-butanol-to-acetic-acid molar ratio=1.1/1, catalyst loading=0.25% (molar percentage of acetic acid), reaction time 2.5 h, 80-85 ℃ and 2.5 ml cyclohexane as water-carrying agent. The experimental results showed that methanesulfonates of lanthanide, copper, calcium exhibited the highest catalytic activity , with butyl acetate yield of over 90.0%. Methanesulfonate of copper, calcium, zinc can be reused by simple phase-separation without remarkable loss of catalytic activity.
【Fund】: 国家自然科学基金 (No. 2 0 2 73 0 2 8);; 辽宁省自然科学基金 (981 0 3 0 1 3 0 2 )资助课题
【CateGory Index】: O643.3
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Chinese Journal Full-text Database 1 Hits
1 GONG Hong~1,WANG Min~2,JIANG Heng~1,WANG Zhi-chang~2(1.School of Petroleum and Chemical Technology,Liaoning University of Petroleum and Chemical Technology,Fushun 113001,China;2.Department of Chemistry,School of Sciences,Northeastern University,Shenyang 110004,China);Synthesis of Allantoin without Catalyst[J];Chinese Journal of Synthetic Chemistry;2006-04
Chinese Journal Full-text Database 6 Hits
1 ZHAO Jing lian ZHANG Guo hua (College of Chemical Engeering,Xian Jiaotong University,Xian 710049,China);Synthesis of Allantoin by Solid Superacid SO_4~(2-)/TiO_2[J];China Surfactant Detergent & Cosmetics;2000-06
2 LIU Shi-fei 1 , LEI Guo-jian 2 , HUANG En-cai 1 , WANG Qing-hai 1 (1.Institute of Chemical Engineering , Zhengzhou University , Zhengzhou 450002 , China ; 2.Henan Chemical Industry Research Institute , Zhengzhou 450052 , China);Production Process of Allantoin and Its Application[J];Henan Chemical Industry;2003-03
3 CAI Zhao-sheng~1,WANG Jin-tang~1,QIU Li-gan~2,WANG Mao-yuan~2(1. School of Science, Nanjing University of Technology, Jiangsu Nanjing 210009, China;2. Department of Chemistry, Yancheng Normal College, Jiangsu Yancheng 224002, China);Study on the Synthesis of Allantoin with a Composite Acid of PTSA/H_3PO_4 as Catalyst[J];Huaxue Shijie (Chemical World);2004-01
4 $ Wang Weiqing Xing Yanfeng Wei Yanxuang (Department of Chemical Engineering,Harbin Engineering University,Harbin,150001);STUDIES ON THE SYNTHESIS OF ALLANTION USING TUNGSTOPHOSPHORIC ACID AS CATALYSTS[J];CHEMICAL RESEARCH AND APPLICATION;1996-04
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6 Chen Xiaoyan, Ma Lanying, Liu Wanyi, Tian Danian(School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021,China);Synthesis of Allantoin Catalyzed by Big-Hole Resin Supported Ce(SO_4)_2[J];Journal of Ningxia University(Natural Science Edition);2004-03
【Secondary References】
Chinese Journal Full-text Database 2 Hits
1 SHEN Xiang-zhong,XIE Shan-mei,HU Ting(Department of Chemistry and Material Science,Hunan Institute of Humanities,Science and Technology,Loudi,417000,China);Preparation of Nano-sized SO_4~(2-)/TiO_2/La~(3+) Rare-earth Solid Superacid and Study on Synthesis of Allantoin[J];Journal of Hunan Institute of Humanities, Science and Technology;2008-02
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