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《Acta Photonica Sinica》 2011-04
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Third-order Nonlinear Optical Properties Study of [(C_3H_7)_4N][Au(C_3S_5)_2] Applied to All-optical Switches

LI Guo-chao~a,REN Quan~a,WANG Xin-qiang~b,YANG Hong-liang~a,CHEN Jing-wei~a,CAI Ning-ning~b(a.School of Information Science and Engineering;b.State Key Laboratory of Crystal Materials,Shandong University,Jinan 250100,China)  
A novel novel dmit2-salt: [(C3H7)4N][Au(C3S5)2] was synthesized.Its acetonitrile solution with concentration 1.0 ×10-3 mol/L was prepared.The thin film with [(C3H7)4N][Au(C3S5)2]-doped in PMMA was fabricated spin-coating on a quartz substrate.The third-order optical nonlinearities of sample solution and film were investigated by using the laser Z-scan technique with 20 ps pulses width at 1 064 nm.The experimental results show that the third-order nonlinear susceptibility χ(3) improves an approximate 3 orders of magnitude by the PrAu film over the solution.The nonlinear refraction coefficient n2 and the third-order nonlinear susceptibility χ(3) of the PrAu film were obtained to be 1.76×10-15 m2/W and 9.37×10-10 esu,respectively.The results suggest that PrAu will be a promising material for all-optical switching devices.
【Fund】: 国家自然科学基金(No.60778037 No.50772059);; 高等学校全国优秀博士学位论文专项资金(No.200539)资助
【CateGory Index】: O437
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【Citations】
Chinese Journal Full-text Database 4 Hits
1 XIAO Bing-gang1,2,SHEN Su2,DI Yue-miao2(1 College of Info Science and Engineering,China Jiliang University,Hangzhou 310018,China)(2 State Key Laboratory for Modern Optical Instrumentation,Joint Laboratory of Optical Communications of Zhejiang University,Center for Optical and Electromagnetic Research,Zhejiang University,Hangzhou 310027,China);Theoretical Analysis for Measuring Optical Parameters of Negative-refractive-index Film with Prism Coupler[J];Acta Photonica Sinica;2007-07
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【Co-citations】
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1 HU Bao-jing1,HUANG Ming,ZHANG Jian-long1,PENG Jin-hui2(1 School of Information Science and Engineering,Yunnan University,Kunming 650091,China)(2 Faculty of Materials and Metallurgical Engineering,Kunming University of Science and Technology,Kunming 650093,China);Focus Character for Metamaterial Volume with Regular Polygon Structure under Light Irradiation[J];Acta Photonica Sinica;2009-05
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4 WU, Wei-Wei JIANG, Yi-Ming GUO, Feng ZHONG, Cheng LIU, Ping LI, Jing* (Department of Materials Science, Fudan University, Shanghai 200433);Influence of Humidity on Chemical Transport Behavior in Cu/TCNQ Metal-organic Thin Film[J];Acta Chimica Sinica;2005-20
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