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《JOURNAL OF HEBEI UNIVERSITY(NATURAL SCIENCE)》 1996-04
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Kinetics and Mechanism of Oxidation of Aminoacetic Acid by Diperiodatocuprate(Ⅲ) Complex in Alkaline Medium

Shan Jinhuan Zhao Jianguo Shen shigang Lu Yanmin (Department of Chemistry, Hebei University, Baoding 071002)  
The kinetics of oxidation of aminoacetic acid by diperiodatocuprate(Ⅲ) comples ion was studied by spectrophotometry in alkaline medium. The reaction rate showed first order dependance in oxidant. It was found that the pesudo-first-order (》) rate costant k obs increases with the increase in and increases with the increase in OH - , but decreases with the increase in . Linear relationships between 1/k obs and 1/ and between 1/k obs]and IO - 4 were observed. There is a neagative salt effect. A plausible mechanism involving free redical has been proposed. The rate equations derived from the mechanism explained all the experimental results satisfactorily. The rate constants and activation parameters of the rate determining step are 2.73×10 -2 s -1 (297.2K), 5.43×10 -2 s -1 (301.2K), 6.96×10 -2 s -1 (303.2K), Ea=100.39kJ·mol -1 , △S -=141.25J·K -1 mol -1 , at 298K respectively.
【Fund】: 河北省自然科学基金
【CateGory Index】: O643.132
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【References】
Chinese Journal Full-text Database 2 Hits
1 WANG Li-ping1,2,SHAN Jin-huan1,SHEN Shi-gang1,XU Ming-yuan2,GE Xu-sheng2(1.Key Laboratory of Analytical Science and Technology of Hebei Provience,College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China;2.Department of Chemistry,Baoding University,Baoding 071000,China);Kinetics and Mechanism of Oxidation of Some Amino Acid Salts by Ditelluratocuprate(Ⅲ) with Spectrophotometry in Alkaline Medium[J];河北大学学报(自然科学版);2008-06
2 WANG Li-ping~(1,2) SHAN Jin-huan~2, SUN Han-wen~2 (1.Department of Chemistry, Baoding Teachers College, Baoding 071051, China; 2.College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China);Existence of Transition Metals in Highest Oxidation State Complex[J];河北大学学报(自然科学版);2004-03
【Citations】
Chinese Journal Full-text Database 1 Hits
1 Shan, Jin-Huan Liu, Tie-Ying(Department of Chemistry, Hebei University, Baoding, 071002);Kinetics and Mechanism of Substitution Reactions of Bis(N,N-Diethyldithiocarbamato) alkylxanthatocobalt (Ⅲ) with Dipropylamine and Di-n-butylamine in Methanol[J];化学学报;1994-11
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 Fan Li1,Shan Jinhuan2(1.School of National Defense Science and Technology,Southwest University of Science and Technology,Mianyang 621010;2.College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China);Kinetics of Catalyzed the Cr (VI) Oxidation of Malic Acid and Glycol with Spectrophotometry[J];广东化工;2010-11
2 WANG Li-ping1,2,SHAN Jin-huan1,SHEN Shi-gang1,XU Ming-yuan2,GE Xu-sheng2(1.Key Laboratory of Analytical Science and Technology of Hebei Provience,College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China;2.Department of Chemistry,Baoding University,Baoding 071000,China);Kinetics and Mechanism of Oxidation of Some Amino Acid Salts by Ditelluratocuprate(Ⅲ) with Spectrophotometry in Alkaline Medium[J];河北大学学报(自然科学版);2008-06
3 SHAN Jin-huan,WANG Fang,HUO Shu-ying,WANG He-ye(College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China);A Kinetic Study on the Oxidation of 1,2-Butanediol by Chromium(Ⅵ)[J];河北大学学报(自然科学版);2008-05
4 SHAN Jin-huan,HAN Chong,HUO Shu-ying,FAN Li (College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China);Kinetics and Mechanism of Oxidation of 2-Amino-1-butanol by Diperiodatocuprate(Ⅲ) in Alkaline Medium[J];河北大学学报(自然科学版);2008-01
5 SHAN Jin-Huan,WEI Hai-Ying, WANG Li, SHEN Shi-Gang, LIU Bao-Sheng, SUN Han-wen (College of Chemistry and Environmental Science, Hebei University,Baoding 071002, China);Kinetics and mechanism of oxidation of aspartic acid by dihydrodiperiodatonickelate (IV) complex in alkaline aqueous medium[J];河北省科学院学报;2001-02
6 SHAN Jin huan, LIU Bao sheng, ZHANG Hui li, SHEN Shi gang (Department of Chemistry,Hebei University,Baoding 071002, China);Kinetics and mechanism of oxidation of potassium pyruvate by diperiodato cuprate (Ⅲ) in alkaline medium[J];河北省科学院学报;1999-03
7 Shan Jinhuan\ Han Guoqing\ Shen Shigang\ He Yahong (Dept. of Chemistry, He Bei University, Baoding, 071002);Kinetic Study of Oxidation Reaction of Tetrahydrofurfury Alcohol by Ditelluratoargentate(Ⅲ)in Alkaline Medium by Spectrophotometry[J];广东工业大学学报;1997-S1
8 Shan Jinhuan Shen Shigang Qie Lujiang Song Yongmei (Department of Chemistry, Hebei University, Baoding 071002);Kinetics and Mechanism of Oxidation of Tetrahydrofurfuryl Alcohol by Ditelluratocuprate( Ⅲ) Ion in Alkaline Medium[J];河北大学学报(自然科学版);1997-04
9 SHAN Jin - Huan QIE Lu - Jiang GUO Xin - Shuang(Department of Chemistry, Hebei University, Baoding ,071002);Kinetics and Mechanism of Oxidation of Glycol by Ditellurato-Cuprate(III)in Alkaline Medium[J];化学学报;1997-05
10 Shan Jinhuan Zhao Jianguo Shen shigang Lu Yanmin (Department of Chemistry, Hebei University, Baoding 071002);Kinetics and Mechanism of Oxidation of Aminoacetic Acid by Diperiodatocuprate(Ⅲ) Complex in Alkaline Medium[J];河北大学学报(自然科学版);1996-04
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 WANG Li-ping~(1,2),SHAN Jin-huan~1,XU Ming-yuan~2,SHEN Shi-gang~1,GE Xu-sheng~2(1.Key Laboratory of Analytical Science and Technology of Hebei Province,College of Chemistry and Environmental Science,Hebei University,Baoding 071002,China;2.Department of Chemistry,Baoding Teachers College,Baoding 071051,China);Kinetics and Mechanism of Oxidation of 1,3-propylene Glycol by Diperiodatocuprate(Ⅲ) with Spectrophotometry in Alkaline Medium[J];河北大学学报(自然科学版);2006-06
2 Yuan Baoling 1, Qu Jiuhui 1, Wang Min 2 (1. SKLEAC, Research Center for Eco Environmental Sciences, Chinese Academy of Sciences, Beijing 100085 China, ; 2. Resources and Environment college, Beijing Foresty University, Beijing 100083, China );Degradation of Cyanobacterial Peptide Hepatotoxins by Ferrate[J];环境科学;2002-02
3 SHAN Jin Huan*,1 WANG Li2 WEI Hai Ying1 SHEN Shi Gang1 SUN Han Wen1 (1College of Chemistry and Environment Science, Hebei University, Baoding 071002) (2China Lucky Film Corporation, Hebei, Baoding 071051;Kinetics and Mechanism of Oxidation Ethylene Glycol Monoethylether by Ditelluratocuprate(Ⅲ)in Alkaline Medium[J];无机化学学报;2002-02
4 SHAN Jin-Huan,WEI Hai-Ying, WANG Li, SHEN Shi-Gang, LIU Bao-Sheng, SUN Han-wen (College of Chemistry and Environmental Science, Hebei University,Baoding 071002, China);Kinetics and mechanism of oxidation of aspartic acid by dihydrodiperiodatonickelate (IV) complex in alkaline aqueous medium[J];河北省科学院学报;2001-02
5 Yuan Baoling 1,Qu Jiuhui 1,Zhang Jinsong 2,Ge Xu 2,Liang Ming 2,Tian Baozhen 1(1 State Key Laboratory of Environmental Aquatic Chemistry, Research Center for Eco Environmental Sciences, Chinese Academy of Sciences, Beijing 100085, China E mail:;The Efficiency of Algae Removal from Drinking Water by Ferrate[J];环境科学;2001-02
6 SHAN Jin-huan ,WANG Li ,SHEN Shi-gang , LIU Bao-sheng,SUN Han-wen (College of Chemistry and Environment Science, Hebei University ,Baoding 071002,China);Kinetics of Oxidation of Malic Acid by Ditelluratoargentate(Ⅲ) Ion in Alkaline Medium[J];河北大学学报(自然科学版);2001-01
7 LIU Ying-hai, ZHANG Jin-song, LI Wei-ping (College of Chemistry and Environment Science, Hebei University, Baoding 071002,China);Graft Copolymerization of Methyl Acrylate onto Soluble Starch Initiated with Potassium Diperiodatocuprate(Ⅲ)[J];河北大学学报(自然科学版);2001-01
8 SHAN Jin Huan WANG Li SHEN Shi Gang SUN Han Wen (Department of Chemistry, Hebei University , Baoding 071002) LIU Bao Sheng (Center of Physical and Chemical Analysis , Hebei University, Baoding 071002);Kinetics and Mechanism of Oxidation of Ethylene Glycol Monomethyl Ether by Ditelluratocuprate? in Alkaline Medium[J];无机化学学报;2000-06
9 SONG Wen Yu LIU Hong Mei (Department of Chemistry, HeBei University, Baoding 071002);Kinetics and Mechanism of Oxidation of Cyclohexanone by Diorthotelluraocuprate(Ⅲ) Complex Ion in Alkaline Medium[J];无机化学学报;2000-04
10 LI Zhi-Ting,CHANG Qing,LI Bao-Wen,YANG Li-Ting,WANG An-Zhou (Department of Chemistry,Hebei University,Baoding 071002,China);Kinetics and Mechanism of Oxidation of Ethylenediamine by Dihydroxydiperidatonickelate(Ⅳ) Complex Ion in Alkaline Medium[J];高等学校化学学报;2000-05
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 CHEN Xiao-bo,WU Rong,ZHAI Guang-qun,JIANG Bi-biao(Department of Materials Science and Engineering,Changzhou University,Changzhou 213164,China);Supernormal-valence Transition Metal-catalyzed Redox-initiated Radical Polymerization[J];高分子通报;2011-06
【Secondary Citations】
Chinese Journal Full-text Database 1 Hits
1 Wang Anzhou Huo Shouqin (Department of chemistry,Hebei University,Baoding);STUDY ON THE KINETICS OF THE REACTIONS BETWEEN TRIS (ALKYLXANTHATO) COBALT (Ⅲ) AND DIMETHYLAMINE BY HIGH-PERFORMANCE LIQUID CHROMATOGRAPHY[J];物理化学学报;1987-04
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