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《Journal of Hebei Normal University(Natural Science Edition)》 2008-03
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Syntheses of Spherical Molecularly Imprinted Polymers and Their Molecular Recognition for Sulfadiazine

JIANG Ji-gang,WANG Lei,WEI Guang-cheng (Department of Chemistry,Binzhou Medical College,Shandong Binzhou 256600,China)  
Taking sulfadiazine as template molecular,spherical molecularly imprinted polymer(MIP) were prepared according to molecularly imprinted technology.By Scatchard mode,the dissociation constant of MIP at binding site is 8.6 μmol/L,and the max binding capacity of MIP is 185.7 μmol/g.Binding isotherm equation tallies with Longmuir equation,and the selective binding ability of MIP decreases with the increase of the polarity in solution,which indicate that non covalent bond plays a great role in molecular recognition.
【Key Words】： sulfadiazine molecularly imprinted polymer molecule recognition
【Fund】： 山东省卫生厅科技基金(2003CAICFB4);; 滨州医学院科技基金(BY2006KJ12)
【CateGory Index】： O631.3
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1 XULi 1 ,HE Jian-feng 2 ,LIULan 2 ,DENG Qin-ying 2 (1.Department of Applied Chemistry,South China Agricultural University,Guangzhou510275,China; 2.Department of Chemistry,Sun Yat-sen University,Guangzhou510275,China);Preparation and Characterization of Molecular Imprinting Polymer with Quinine as the Template[J];Journal of Instrumental Analysis;2005-01
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1 YU Ying,SU Li-qiang (Cellege of Chemistry and Chemical Engineering,Qiqihar Univesity,Qiqihar 161006,China);Study on the preparation and recognition property of molecular imprinted polymer of salicylanilide[J];Chemical Engineer;2009-04
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1 LI Li~1,HU Shu-Guo~1,HE Xi-Wen~(1*),LI Wen-You~1,CHEN Lang-Xing~1,ZHANG Yu-Kui~(1,2*)(1.College of Chemistry,Nankai University,Tianjin 300071,China;2.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China);Solid-phase Extraction of Active Component of Chinese Traditional Medicine Fisetin by Using Molecularly Imprinted Polymers[J];Chemical Journal of Chinese Universities;2006-04
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