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《China Synthetic Fiber Industry》 2006-05
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Modeling and simulation for solid-state polymerization of nylon 6

Liu Zhenhong, Wang Chaosheng, Huang Nanxun,Tang Zhilian (College of Environmental Science and Engineering, Donghua University, Shanghai 200051)  
The kinetic model for solid-state polymerization of nylon 6 which was controlled by reversible reaction and small molecule diffusion was established based on the mechanism of nylon 6 solid-state polymerization. The kinetic and thermodynamic parameters were decided. The results obtained from the computer simulation experiment showed that the high polymerization temperature , the small size and the high initial molecular weight of prepolymers were helpful to the growth of molecular weight of nylon 6 during the solid-state polymerization.
【CateGory Index】: TQ323.6
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Chinese Journal Full-text Database 7 Hits
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