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《China Synthetic Fiber Industry》 2013-01
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Synthesis and properties of fluorine-containing hyperbranched polyester

Sun Yiming,Xie Xia,Bi Xiaoyun (School of Chemical and Environment Engineering,Hubei University of Technology,Wuhan 430068)  
The fluoride-containing hyperbranched polyester was prepared by the terminal group modification of hyperbranched polyester with tridecafluorooctanoic acid.The polymer was characterized and analyzed by Fourier transform infrared spectrometry and differential scanning calorimetry.The results showed that tridecafluorooctanoic acid was successfully grafted on hyperbranched polyester;the fluoride-containing hyperbranched polyester had the glass transition temperature of-20.5 ℃ and the solution thereof exhibited low viscosity and good film forming ability as the solid content was up to 70%;and the film had adhesion grade 1,flexibility 1 mm,pencil hardness 2 H,anti-impact strength 4.9 J/cm2,water contact angle 105° and favorable surface hydrophobicity.
【CateGory Index】: TQ323.41
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 Wang Li,Tong Shenyi(Wuhan Institute of Technology,Hubei Key lab.of Novel Reactor and Green Chemical Technology,Wuhan 430074,China);Synthesis and Modification of Hyperbranched Polyester[J];Paint & Coatings Industry;2006-10
2 Wang Zhi_guo and Tong Shen_yi;The use of ultra-branched polymers in coatings[J];China Paint;2003-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 CUI Chunni,CHEN Weixing (School of Material and Chemical Engineering,Xi'an Technological University,Xi'an 710032);Research Progress in Preparation and Application of Hyperbranched Polymers[J];Materials Review;2009-S1
2 HOU Hong-xia,HAO Zhi-feng,WU Ya-hong,LI Hua-gong,YU Jian College of Chemical Engineering and Light Industry,Guangdong University of Technology,Guangzhou 510006,China;Synthesis and properties of hydroxyl-terminated saturated polyester modified by titanium-doped silicone resin[J];Electroplating & Finishing;2011-04
3 Li Zhineng,Zhang Li,Dong Guilan,Hu Yangshan(School of Chemistry and Environment,South China Normal University,Guangzhou 510006,China);Synthesis of Hyperbranched Polyester and as Flexibilizer for EpoxyResin[J];Guangdong Chemical Industry;2012-06
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8 TIAN Ling~(1,2),QIANG Xi-huai~(1),QIAO Yong-luo~2,ZHANG Chuan-bo~(1),SHEN Liang~(2*)(1.The College of Resource &Environment,Shaanxi University of Science & Technology,Xianyang 712081,China;2.Jiangxi Key Laboratory of Organic Chemistry,Nanchang 330013,China);Practical Foreground of Highly Branched Macromolecules in the Cleaning Leather Industry[J];Leather Science and Engineering;2006-05
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【Secondary Citations】
Chinese Journal Full-text Database 3 Hits
1 TANG Li Ming , ZHANG Xiao Long, LI Wei, LIU De Shan [WT5”BX](Department of Chemical Engineering, School of Material Science and Engineering, Tsinghua University, Beijing 100084, China) [WT5HZ];Studies on Modification of End Groups of Aliphatic Hyperbranched Polyester[J];Chemical Research In Chinese Universities;2000-12
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3 Wang Zhi_guo and Tong Shen_yi;The use of ultra-branched polymers in coatings[J];China Paint;2003-02
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