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Advances on the Applications of Ethyl and Methyl Trifluoroacetate in Organic Synthesis

Ye Dongju;Zheng Tucai;Ye Shanhai;Wang Xiaoqing;College of Chemical and Material Engineering, Quzhou University;Zhejiang Hai-sheng Chemicals Co.,Ltd;  
This paper first reviewed the preparation of ethyl and methyl trifluoroacetate, then summarized recent researches on their applications in organic synthesis, with particular emphasis on the uses of its major derivative ethyl trifluoacetoacetate, and on their applications in Claisen condensation with ketones to prepare trifluoromethylated β-diones. Future studies should focus on the technology improvement and industrial research especially on the applications of ethyl and methyl trifluoro- acetate as important protecting groups and valuable building blocks.
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