Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Journal of Chemical Industry and Engineering(China)》 1992-02
Add to Favorite Get Latest Update

KINETICS OF HYDROLYSIS OF CARBONYL SULPHIDE IN AQUEOUS SOLUTION OF SODIUM HYDROXIDE

Liu Runjing, Zhang Chengfang, Qin Shujun and Zheng Zhisheng (East China Institute of Chemical Technology, Shanghai 200237)  
Hydrolysis rate of carbonyl sulphide was determined in a bubble reactor at 20-50℃, sodium hydroxide concentration 1. 3130-4. 4038 mol/L and atmospheric pressure. The first-order rate expression for the hydrolysis of carbonyl sulphide is Ink1 =27.90 - 7168/T + 0.56I where, Ncos,Hcos,pcos,i are absorption rate, solubility coefficient and partial pressure at interface of COS respectively. The constant ki is first-order rate-constant of forward reaction and I is ionic strength for initial concentration of NaOH. The apparent activation energy is 59.63 kJ/mol.
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 2 Hits
1 Zhu zibin and Ma Zhihua Lin Shiying, Mitsuho Hirato and (.East China University of Science and Technology, Yoshihiko Ninomiya Shanghai 200237) (Tokyo University of Agriculture and Industry, Tokyo 184, Japan);CHARACTERISTICS OF COAL CHAR GASIFICATION AT HIGH TEMPERATURE (Ⅰ) THE EFFECT OF ASH FUSION ON COAL CHAR GASIFICATION[J];Journal of Chemical Industry and Engineering(China);1994-02
2 Zhu Zibin and Ma Zhihua Lin Shiying, Mitsuho Hirato and (East China University of Science and Technology, Masayuki Horio Shanghai, 200237) (Tokyo University of Agriculture and Industry, Tokyo 184, Japan);CHARACTERISTICS OF COAL CHAR GASIFICATION AT HIGH TEMPERATURE (Ⅱ) THE EFFECT OF PORE STRUCTURE ON COAL CHAR GASIFICATION[J];Journal of Chemical Industry and Engineering(China);1994-02
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Zhang Qing-lin and Guo Han-xian (Research Institute of Coal Chemical Engineering, Taiyuan University of Technology);THE CHARACTERISTIC AND MECHANISM OF DEACTIVATION OF CARBONYL SULFIDE HYDROLYSIS CATALYST[J];Chinese Journal of Catalysis;1988-02
2 LIANG Meisheng 1,2*, LI Chunhu 1, GUO Hanxian 1, XIE Kechang 1 (1 State Key Laboratory of C1 Chemistry and Technology, Research Institute for Chemical Engineering of Coal; 2 College of Architecture and Environmental Engineering, Taiyuan University;Study on Reaction Kinetics of COS Hydrolysis at Lower Temperature[J];Chinese Journal of Catalysis;2002-04
3 LIU Shouxin 1,2 , SUN Chenglin 1* , ZHANG Shirun 2 (1 Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023, Liaoning, China; 2 Northeast Forestry University, Harbin 150040, Heilongjiang, China);Photocatalytic Regeneration of Coal-Based Activated Carbon[J];Chinese Journal of Catalysis;2003-05
4 Liu Shouxin; Wang Yan(NorthCast Forestry University. Harbin 150040. P. R. China); Zheng Wenchao(Zoological Garden of Harbin);Progress in Activated Carbon Regeneration[J];Journal of Northeast Forestry University;2001-03
5 SUN Fu-nan,FENG Qing-xiang ,WU Jiang-hong (Guangming Research & Design Institute of Chemical Industry,Dalian 116031,China);The Production of High Purity Carbonyl Oxysulfide[J];Low Temperature and Specialty Gases;2004-03
6 ZHANG Feng, WU Hongbo, XUE Huaxing, WU Beili, CHEN Jianmin(Department of Environmental Science & Engineering, Fudan University, Shanghai 200433, China);The Photo-oxidation of COS[J];Journal of Fudan University;2003-03
7 XIAO Zhongbin1, ZHANG Yiqun1, MA Jianxin2, ZHOU Wei2, WU Minzhong2(1. Institute of Industrial catalysis, ECUST, Shanghai 200237, China;2. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 200092, China);Hydrolysis of Carbonyl Sulfide over Sulfidized Rare Earth Oxides[J];Journal of Fudan University;2003-03
8 ZHANG Yiqun1 , XIAO Zhongbin1 , MA Jianxin2 , ZHOU Wei2 , WU Minzhong2(1. Institute of Industrial Catalysis, Eeast China University of Science and Technology, Shanghai 200237, China;2. Clean Energy Automotive Engineering Center, Tongji University, Shanghai 200092, China);Effect of O_2 and SO_2 on Hydrolysis of Carbonyl Sulfide over Rare Earth Oxysulfides[J];Journal of Fudan University;2003-03
9 Cheng Qing, Cao Changjun, Yao Xiaohong (Central Laboratory of Ethylene Plant, PetroChina Goup Dushanzi Petrochemicals Company, Dushanzi, 833600);Determination of trace carbonyl sulfur in propylene by gas chromatography with pulsed flame photometric detector.[J];Analytical Instrumentation;2006-02
10 LI Yonggui,JIAN Chao,GE Mingqiao(Key Laboratory of Science & Technology of Eco-Textile,Ministry of Education,Southern Yangtze University,Wuxi,Jiangsu 214122,China);New method of electro-thermal regeneration on activated carbon fiber[J];Journal of Textile Research;2007-02
【Secondary References】
Chinese Journal Full-text Database 10 Hits
1 Chen Shuwen1,2,Zhang Chongmin2,Zhai Yuchun1(1.School of Materials and Metallurgy,Northeastern University,Shenyang 114004,China; 2.School of Materials and Engineering,Anshan University of Science and Technology,Anshan 114044,China);Analysis on carbonous reactivity and structure of remnant coke from gasified plastics[J];Journal of Molecular Science;2005-05
2 Tang Lihua *, Zhu Zibin, Zhao Qingxiang 1) , Zheng Zhisheng, Zhang Chengfang and Ma Luming 1) (Institute of Chemical Technology ECUST, Shanghai 200237) 1) (Institute of Environment Engineering ECUST);Study of Actived Sewage Sludge as Coherent Agent for Briquet of Gasification ——Effect of Dispersion Rate of Sewage Sludge in Fine Coal on Briquet Quality[J];JOURNAL OF EAST CHINA UNIVERSITY OF SCIENCE AND TECHNOLOGY;1998-05
3 Wang Zhiguang1,Yang Xu2,Rao Zhixiong1,Zhang Dexiang1 and Gao Jinsheng1(1.East China University of Science and Technology,Shanghai 200237;2.Pingdingshan Coal Circle Limited Company,Pingdingshan 467000);Gasification Reactivity of Pingdingshan Coal with High Ash Melting Point[J];Coal Chemical Industry;2007-06
4 Gu Xiaohu1,Cao Min1,2,Wang Lanpu2 and Tian Yapeng2(1.Henan Polytechnic University,Jiaozuo 454000;2.Yima Coal Industry Group,Yima 472300);Effect of Ash on Gasification Reactivity[J];Coal Chemical Industry;2009-02
5 Wu Shiyong Gu Jing Li Li Wu Youqing and Gao Jinsheng(Department of Chemical Engineering for Energy Resources,East China University of Science and Technology,200237 Shanghai);EFFECTS OF ASH FUSION ON REACTION ACTIVITY OF SHENFU CHARS AT ELEVATED TEMPERATURES[J];Coal Conversion;2006-04
6 Liu Wen-Bin~(1,2), Lu Xian-Cai~1, Qin Jian-Zhong~2, Wang Chao-Hong~3, Yao Su-Ping~1(ences, Nanjing University, Nanjing, 210093, China; 2. Wuxi Research Institute of Experimental Geology, SINOPEC, Wuxi, 214151, China; 3. Planning and Designing Institute of East China Branch, SINOPEC, Nanjing, 210036, China);Solid Residue of Thermal Simulation Experiment of Laminaria and Its Petroleum Geological Significance[J];Journal of Nanjing University (Natural Sciences);2005-03
7 TANG Li-hua, WU Yong-qiang, ZHU Xue-dong, ZHU Zi-bin (East China University of Science and Technology, Shanghai 200237, China);EFFECT OF CHAR MAKING TEMPERATURE ON CHAR GASIFICATION ACTIVITY IN HIGHER TEMPERATURE[J];Journal of Fuel Chemistry and Technology;2002-01
8 XIANG Yin hua, WANG Yang, ZHANG Jian min, DONG Zhong bing, LI Bin (Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China);STUDY ON STRUCTURAL PROPERTIES AND THEIR AFFECTING FACTORS DURING GASIFICATION OF CHARS[J];Journal of Fuel Chemistry and Technology;2002-02
9 LI Qing-feng~1, FANG Yi-tian~1, ZHANG Jian-min~2, WANG Yang~1, SHI Ming-xian~3, SUN Guo-gang~3 (1. Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan030001, China; 2. University of Shanghai for Science and Technology, Shanghai200093, China; 3. University of Petroleum, Beijing100083, China);Changes of pore structure and gasification activity during steam-gasification of petroleum coke[J];Journal of Fuel Chemistry and Technology;2004-04
10 WU Shi-yong,LI Li,GU Jing,WU You-qing,GAO Jin-sheng(Department of Chemical Engineering for Energy Resources,East China University of Science and Technology,Shanghai 200237,China);Gasification reactivity of rapid and slow pyrolyzed Shenfu chars with CO_2 at high carbon conversions and elevated temperatures[J];Journal of Fuel Chemistry and Technology;2006-04
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved