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《Journal of Chemical Industry and Engineering(China)》 2002-01
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ADSORPTION OF ALKANE-ALCOHOL BINARY MIXTURE LIQUID ON MOISTURE-CONTAINING RESINS

MA Liping,CHEN Jingde and DAI Xiaoyan (Department of Chemical Engineering,Sichuan University,Chengdu 610065,Sichuan,China)  
In this paper,the adsorption of alkane-alcohol binary non-aqueous solutions on DOO1 and TS-TR resins is investigated.Local adsorption isotherms (20?℃) from binary liquid mixture consisting of butanol-heptane,ethanol-hexane on two kinds of resins with a fixed moisture content are measured respectively.Based on NBP-a model,an isotherm adsorption model was developed,and energy distribution density function is developed with Stieltjes transform.Results show that surface energy heterogeneity of adsorbent and nonideality of solution play an important role in the adsorption.Moisture content in resin also affects on its surface energy heterogeneity.The surfac energy heterogeneity of polar DOO1 resin increased with moisture content,and the surface energy heterogeneity of non-polar TS-TR resin also changes significantly with moisture content.Calculated results with the adsorption model agree with the results of experiments.
【CateGory Index】: TQ202
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