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《Journal of East China University of Science and Technology》 2005-05
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Molecular Imprinted Polymers of Dibenzoyl-L-Tartaric Acid with Recognition Properties Prepared by Thermal Polymerization Method Ⅰ.Optimizing the Thermal Polymerization Conditions

YANG Zuo-guo,XU Zhen-liang(Research Institute of Chemical Engineering,East China University of Science and Technology,Shanghai 200237,China)  
Using a functional monomer(methyl methacrylate,acrylamide,ethyl acrylate and acrylic acid) and a crosslinker(glycol dimethyacrylate), molecularly imprinted polymers(MIPs) of dibenzoyl-L-tartaric acid(L-DBTA) with recognition properties were prepared by thermal polymerization method in the presence of a template(L-DBTA) in acetonitrile solution.The effects of different functional monomers,concentrations of functional monomers,cross-linker concentrations,polymerization temperatures,polymerization times,different solvents on the MIPs' recognition properties were discussed.The binding(experiments) and high-performance liquid chromatographic(HPLC) analysis of molecularly imprinted polymers(MIPs) of L-DBTA with recognition properties were conducted to evaluate the influences of various factors on DBTA binding.The experimental results indicate that the MIPs has higher L-DBTA binding(ability) than D-DBTA's and also higher than corresponding non-imprinted polymers.The binding ability is the highest at template(L-DBTA): functional monomer(MMA):crosslinker(GDMA) 1∶4∶20(molar ratio) as polymerization temperature is(60 °C) and polymerization time is 48 h.Based on the optimal experimental results,the highest separation factor(α) of L-DBTA/D-DBTA of the MIPs can be 2.79.
【Fund】: 国家重点基础研究发展计划(973计划)资助(2003CB615705)
【CateGory Index】: TQ316.311
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