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《Journal of South China University of Technology(Natural Science)》 2001-01
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Peroxone Oxidation and Reaction Kinetics of Benzene in Aqueous Solutions

Zhong Li 1 Zhan Huai_yu 2 (1. Department of Chemical Engineering, South China University of Technology, Guangzhou 510640, China; 2. State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China)  
A kinetic model has been developed for the degradation of organic pollutants considering both decomposition of ozone molecules and interaction between ozone and hydrogen peroxide for formation of hydroxyl radical and subsequent reactions. Rate equations were derived for depletion of ozone and pollutants in the advanced oxidation processes (known as the peroxone oxidation). Experiments were carried out at 298 K in the pH range of 3 to 9. Kinetic data obtained experimentally from the hydrogen peroxide_ozone reaction and peroxone oxidation of benzene were analyzed by using the proposed rate equations. The experimental results are in agreement with the theoretical model in basic solutions.
【Fund】: 广东省自然科学基金!(990 6 42 );; 华南理工大学制浆造纸工程国家重点实验室开放基金资助项目&&
【CateGory Index】: X131
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【References】
Chinese Journal Full-text Database 1 Hits
1 Zhong Li1 Qi Ming1 Zhan Huai-yu2(1.College of Chemical and Energy Engineering, South China Univ. of Tech., Guang zhou 510640, Guangdong, China; 2.State Key Lab of Paper and Pulp Engineering, South China Univ. of Tech., Guang zhou 510640, Guangdong, China);Degradation of Vinyl Chloride in Water by the Chemical Oxidation of O_3/H_2O_2 and Its Kinetics[J];Journal of South China University of Technology(Natural Science);2004-12
【Co-references】
Chinese Journal Full-text Database 2 Hits
1 Zhong Li;Kuo Chiang Hai;Zappi Mark Edward(Department of Chemical Engineering of South China University of Technology,Guangzhou 510641)(Department of Chenmical Engineering Mississippi State University MS 39762 USA);EXPERIMENTAL STUDY OF LIQUID PHASE OXIDATION OF TRICHLOROETHYLENE WITH OZONE[J];Journal of Chemical Industry and Engineering(China);1998-01
2 Zhong Li (College of Chem Eng.,South China University of Technology,Guangzhou,510641) C.H.Kuo (Dept. of Chem. Eng.,Mississippi State University,MS39762 USA);Advanced Oxidation Process of Chlorophenol Wastewater by Ozone-Hydrogen Peroxide and Its Kinetics[J];CHINA PULP & PAPER;2000-03
【Secondary References】
Chinese Journal Full-text Database 1 Hits
1 Xie Wen-yu Zhong Li(School of Chemical and Energy Engineering,South China Univ.of Tech.,Guangzhou 510640,Guangdong,China);Pilot Test of Ethylene Wastewater Treated by Coupling Biological Filter and Ozonization[J];Journal of South China University of Technology(Natural Science Edition);2007-06
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