Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《Chemistry》 2012-09
Add to Favorite Get Latest Update

Preparation and Application of Rhein Magnetic Molecularly Imprinted Polymer

Liu Yunan1,2,Zhang Zhaohui1,2,3*,Zhang Minglei1,Chen Xing1,Chen Hongjun1,Nie Lihua3(1Key Laboratory of Hunan Forest Products and Chemical Industry,Jishou University,Zhangjiajie 427000; 2College of Chemistry and Chemical Engineering,Jishou University,Jishou 416000; 3State Key Laboratory of Chemo/Biosensing and Chemometrics,Hunan University,Changsha 410082)  
Rhein magnetic molecularly imprinted polymer(Fe3O4@SiO2@MIP) was prepared based on magnetic particles by using rhein as the template molecule,phenyl and amino silanes as binary functional monomers and tetraethyl orthosilicate(TEOS) as cross-linking agent.The Fe3O4@SiO2@MIP was characterized by SEM and IR.The results showed that rhein imprinted layer was grafted onto the magnetic particles surface successfully.The Fe3O4@SiO2@MIP has uniform cube structure and the thickness of imprinted shell is about 75~100 nm.Combined with magnetic solid phase extraction(M-SPE) and HPLC technology,the imprinted material employed as stationary phase was used to separate,enrich and detect rhein,emodin,chrysophanol and physcion from kiwi fruit root extractives successfully.
【Key Words】: Magnetic molecularly imprinted polymer Rhein Magnetic solid phase extraction
【Fund】: 国家自然科学基金项目(21005030);; 湖南省教育厅重点项目(10A099);; 十二·五国家科技支撑计划项目(2011BAD10B01);; 湖南省高校林产资源化学与林化产品开发科技创新团队支持计划资助
【CateGory Index】: O631.3
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 1 Hits
1 YANG Cai-ling,RAO Hong-hong,HE-Lijun,HUO Cai-xia,ZHANG Ming(College of Chemistry and Environmental Science,Lanzhou City University,Lanzhou Gansu 730070);Synthesis and Properties of the Rhein Molecularly Imprinted Polymers[J];Journal of Gansu Normal Colleges;2013-02
【Citations】
Chinese Journal Full-text Database 10 Hits
1 LU Chun-Yang~1,WANG Hua-Fang~1,HE Xi-Wen~1*,CHEN Lang-Xing~1,LI Wen-You~1,ZENG Xian-Shun~1,ZHANG Yu-Kui~1,2 (1.Department of Chemistry,State Key Laboratory of Elemento-Organic Chemistry,Nankai University, Tianjin 300071,China; 2.Dalian Institute of Chemical Physics,Dalian 116011,China);Molecularly Imprinted Polymer with Bi-functional Monomers of Calix Arene Derivative and Acrylamide for Selective Recognition of Hydantoin-based Compounds[J];Chemical Research In Chinese Universities;2005-10
2 WANG Ying,LI Nan (College of Science,China Agricultural University,Beijing 100193,China);Molecular imprinting technology and its application[J];Chemical Industry and Engineering Progress;2010-12
3 LUAN Chonglin1,LI Mingjie1,2,LI Zhongjin2,SU Xiuxia2,JIANG Xiaohua1(1Department of Fine Chemicals & Materials,Shenzhen Polytechnic College,Shenzhen 518055,Guangdong,China; 2 Key laboratory of Auxiliary Chemistry & Technology for Chemical Industry,Ministry of Education, School of Chemistry and Chemical Engineering,Shaanxi University of Science & Technology, Xi'an 710021,Shaanxi,China);Progress of molecularly imprinted electrochemical sensor[J];Chemical Industry and Engineering Progress;2011-02
4 LI Wenchao1 WANG Yonghua2 SUN Cheng1 YANG Shaogui1(1.School of the Environment,State Key Laboratory of Pollution Control and Resource Reuse,Nanjing University,Nanjing,210093,China; 2.School of the Environment,Key Laboratory of Integrated Regulation and Resource Department on Shallow Lakes,Hohai University,Nanjing,210098,China);THE DEVELOPMENT OF MOLECULARLY IMPRINTED TECHNIQUE COUPLED WITH SOLID PHASE MICROEXTRACTION[J];Environmental Chemistry;2011-09
5 LIAN Hui-ting,CHEN Juan-juan,XUE Yan,LIU Bin(College of Material Science and Engineering,Huaqiao University,Quanzhou 362021,China);Electrochemcial Characteristic of Monocrotophos Molecularly Imprinted Sensor[J];Journal of Huaqiao University(Natural Science);2011-02
6 WU ChengLin,HE Huan,GAO HongJun,LIU Gan,MA RuJiang,AN YingLi & SHI LinQi Key Laboratory of Functional Polymer Materials,Ministry of Education;Institute of Polymer Chemistry,Nankai University,Tianjin 300071,China;Synthesis of Fe_3O_4@SiO_2@polymer nanoparticles for controlled drug release[J];Scientia Sinica(Chimica);2010-03
7 CHEN Xiao-xiao,YANG Shang-jun,BAI Shao-yan(Institute of Materia Mdeica,Shandong Academy of Medical science,Ji′nan 250062);The progress of research on chemical constituents and pharmacological activites for the root of Actinidia chinensis planch.[J];Qilu Pharmaceutical Affairs;2009-11
8 HUANG Xiaodong, KONG Liang, LI Xin, CHEN Xueguo, GUO Baochuan, ZOU Hanfa(National Chromatographic R. & A. Center, Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116011, China);Preparation of Molecularly Imprinted Monolithic Capillary Column for Separation of Diastereomers of Cinchona Alkaloids by Pressure-Assisted Capillary Electrochromatography[J];Chinese Journal of Chromatography;2003-03
9 CHEN Qiong hua,DAI Han Song and SU Xue liang (1. Chinese University of Pharmacy, Nanjing 210010,China; 2. Chengdu Institute of Orgasmic Chemistry,Chinese Academy of Sciences ,Chengdu 610041,China; 3. Tianjin Medical University;STUDIES ON CHINESE RHUBARB XXXI.Improved Method for Systematic Isolation of Anthraquinone Derivatives from Rhubarb[J];Natural Product Research and Development;2001-03
10 HUANG Yun hong, ZHEN Yong su (Institute of Medicinal Biotechnology, Chinese Academy of Medical Sciences and Pekin Union Medical College, Beijing 100050, China);RHEIN INDUCES APOPTOSIS IN CANCER CELLS AND SHOWS SYNERGY WITH MITOMYCIN[J];Acta Pharmaceutica Sinica;2001-05
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LI Hong-xia et al(Life Science College of Tarim University,Alaer,Xinjiang 843300);Comparative Study on the Optimum Extraction Methods of Rheum[J];Journal of Anhui Agricultural Sciences;2008-29
2 SHAO Jing et al (Department of Pharmacy,Gansu College of Traditional Chinese Medicine,Lanzhou,Gansu 730000);Research Progress on the Extraction and Purification Process of Anthraquinone in Rheum[J];Journal of Anhui Agricultural Sciences;2010-11
3 LIU Ping-xin1,ZHANG Ya-fei1,YANG Jing1,MENG Qian2,MA Wei-qing1,REN Yue-ming1,2(1.College of Material Science and Chemical Engineering,Key Laboratory of Superlight Materials & Surface Technology, Ministry of Education,Harbin Engineering University,Harbin 150090,China;2.State Key Laboratory of Urban Water Resource and Environment,Harbin Institute of Technology,Harbin 150001,China);Study on preparation and characters of BPA molecular imprinting adsorbent[J];Materials Science and Technology;2012-01
4 LI Hong-ya,LI Shu-na,ZHU Bao-cheng(College of Life Science,Agricultural University of Hebei,Baoding 071001,China);Optimization of extract conditions for emodin from Chinese rhubarb[J];Journal of Agricultural University of Hebei;2010-06
5 YANG Xin1,2,ZHANG Hua1,DONG Aijun1,ZHANG Yingchun1,ZHAO Haitian1,YAO Lei1,SHE Yongxin2,WANG Jing2(1.School of Food Science and Engineering,Harbin Institute of Technology,Harbin 150090,China;2.Chinese Acedemy of Agricutureal Sciences,Beijing 100081,China);Application of molecular imprinting technology in separation and purification of active ingredients from natural products[J];Journal of Northeast Agricultural University;2011-08
6 Tang Ping-Ping1,Luo Zhao-Feng2,Cai Ji-Bao1,Su Qing-De1 1(Department of Chemistry,University of Science and Technology of China,Hefei 230026) 2(Hefei National Laboratory for Physical Sciences at Microscale and School of Life Sciences,University of Science & Technology of China,Hefei 230027);An Indirect Inhibitive Immunoassay for Detection of Low Concentration Sulfamethoxazole in Aqueous Solution[J];Chinese Journal of Analytical Chemistry;2010-07
7 ZHAO Fang,HUANG Chao-Feng,LIANG Hui,XIONG Wei,CHEN Yan,HU Xin-Yi (College of Chemistry and Chemical Engineering,Shihezi University,Xinjiang Bingtuan Key Laboratory for Green Processing Chemical Engineerin,Shihezi 832000);Interaction of ZnⅡ Complex of Rhein with Bovine Serum Albumin[J];Chinese Journal of Analytical Chemistry;2011-03
8 YAN Zhi-hong, LI Ju-nan~(*), GAO Peng, MAO Xun(College of Chemistry,Xiangtan University,Xiangtan,Hunan 411105);Determination of Trace Rhein at a Carbon Paste Electrode by Adsorption Voltammetry[J];Journal of Analytical Science;2005-04
9 HAN He-you~(*1,2),YOU Zi-han~1,LI Qing~1,CHEN Hao~1(1.Department of Chemistry,College of Science,Huazhong Agriculture University;2.MOA Key Laboratory of Food Safety Evaluation,Wuhan 430070);Progress in the Application of Chemiluminescence Coupled Techniques for Veterinary Drug Residue Analysis[J];Journal of Analytical Science;2005-05
10 Feng Xiwen1,Du Ping2,Zhang Li2(1.School of Material and Chemical Engineering,Sichuan University of Science & Engineering,Zigong 643000;2.School of Chemistry and Pharmaceutical Engineering,Sichuan University of Science & Engineering,Zigong 643000,China);The Application of Molecular Imprinting Technologies on Active Ingredients Extraction and Purifica tion from Natural Drug[J];Guangdong Chemical Industry;2011-02
China Proceedings of conference Full-text Database 1 Hits
1 ZHENG Bao-hui,CAI Zhong-zhan,HUANG Yong, GUO Peng-lin,WANG Ping-sheng {Institute of Chemical Materials,CAEP,Mianyang 621900,China);Application of Molecular Imprinting Technology in the Detection of TNT[A];[C];2011
【Co-references】
Chinese Journal Full-text Database 7 Hits
1 YAN Liu-shui~*,JING Jing,HUANG Zhi-min,WEN Zhen-dong and LIU Feng-tao(Department of Environment and Chemical Engineering,Nanchang Institute of Aeronautical Technology,Nanchang 330034);Preparation of quercetin-imprinted polymer and its property as a sorbent for solid phase extraction[J];Chinese Journal of Analysis Laboratory;2006-05
2 FANG Yan-qing,HONG Mei-hua and CHEN Yuan-tao(Department of Chemistry,Qinghai Normal University,Xining 810008);Preparation and characterization of rhein molecularly imprinted polymeric microspheres[J];Chinese Journal of Analysis Laboratory;2011-12
3 LI Li~1,HU Shu-Guo~1,HE Xi-Wen~(1*),LI Wen-You~1,CHEN Lang-Xing~1,ZHANG Yu-Kui~(1,2*)(1.College of Chemistry,Nankai University,Tianjin 300071,China;2.Dalian Institute of Chemical Physics,Chinese Academy of Sciences,Dalian 116023,China);Solid-phase Extraction of Active Component of Chinese Traditional Medicine Fisetin by Using Molecularly Imprinted Polymers[J];Chemical Journal of Chinese Universities;2006-04
4 ZHANG, Hong-Ge Lü, Jiu-Ru* HE, Yun-Hua DU, Jian-Xiu (School of Chemistry and Materials Science, Shaanxi Normal University, Xi'an 710062);Molecular Imprinting-Chemiluminescence Determination of Phenacetin[J];Acta Chimica Sinica;2005-03
5 GUO Mei-zi, LI Xiao-sheng, SHEN Ding-ming, GUANXiao-qin, XU Hai-rong, GAO Jian. Department of Gastroenterology, The Second Affiliated Hospital, Chongqing Medical University, Chongqing 400010, China;Effect of Rhein on the development of hepatic fibrosis in rats[J];Chinese Journal of Hepatology;2003-01
6 XU Li1,HE Jianfeng2(1.College of Sciences,South China Agricultural University,Guangzhou 510640,China;2.College of Chinese Traditional Medicine,Guangzhou University of Chinese Medicine,Guangzhou 510006,China);Preparation of Hydrophilic Molecularly Imprinted Nano-spheres and the Properties on the Drug Release and Recognition[J];Acta Scientiarum Naturalium Universitatis Sunyatseni;2010-03
7 Guomeizi,Xuhairong ,LixiaoshengDepartmentofGastroenterology ,theSecond AffilicatedHospitalofChongQingMedicalUniversity;Effects of Rhein on Acute Liver Injury of Mice[J];;2002-01
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 YANG Yan-jie et al (Luohe Medical College,Luohe,Henan 462002);Studies on Anti-oxidant and Liver-protective Effects of the Extracts from the Root of Kiwifruit[J];Journal of Anhui Agricultural Sciences;2008-19
2 LIU Shu-juan1,TAN Zheng-chu1,ZHONG Xing-gang1,WU Zai-sheng2,SHEN Guo-li21.Hunan Tea Research Institute,Hunan Academy of Agricultural Science,Changsha 410125,China;2.Chemical and Chemistry Institute,Hunan University,Changsha 410082,China;Studies on a Novel Parathion-Methyl Biosensor Design Based on Acetylcholinesterase Immobilized by Zirconia Nanoparticle[J];Chinese Journal of Sensors and Actuators;2009-05
3 CHEN Fan, CHEN Huan-lin, HE Yi (Coll of Materials Sci & Chem Engin, Zhejiang University, Hangzhou 310027,China);Advances in organophosphorus hydrolase biosensors and theirs applications[J];Journal of Transducer Technology;2004-04
4 WANG Miao1,LIU Ping2,JIA Jin-ping1,HU Xiao-fang1(1.School of Environmental Science and Engineering;2.School of Chemistry and Chemical Technology,Shanghai Jiaotong University,Shanghai 200240);Determination of Benzene and Its Analogues in a Commercial Adhesive by Headspace Solid-phase Micro-extraction Using a Novel Biphenyl-imprinted Sol-gel Coated Fibre[J];Environmental Science & Technology;2006-06
5 Zuo Yanjun, Yu Jianhua, Huang Qibin* (Institute of Chemical Defence, Beijing 102205) Lin Yuan (Center of Molecular Science, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100101);The Preparation of Molecularly Imprinting Nanometer Layer and Its Application in Detecting Nerve Agent Sarin[J];Chinese Journal of Analytical Chemistry;2003-07
6 Lü Yunkai 1,2, Yan Xiuping *1 1(Research Center for Analytical Sciences, College of Chemistry, Nankai University, Tianjin 300071) 2(College of Chemical and Environmental Sciences, Hebei University, Baoding 071002);Preparation and Application of Molecularly Imprinted Sol-Gel Materials[J];Chinese Journal of Analytical Chemistry;2005-02
7 ZHANG Jin1,2,XU Lan1,WANG Ya-Qiong1,L Rui-Hong1 1(Key Laboratory of Luminescence and Real-Time Analysis of Ministry of Education,College of Chemistry and Chemical Engineering,Southwest University,Chongqing 400715)2(Department of Chemistry,Guizhou Education College,Guiyang 550003);Electrochemical Sensor for Bisphenol A Based on Molecular Imprinting Technique and Electropolymerization Membrane[J];Chinese Journal of Analytical Chemistry;2009-07
8 MA Xiu-Ling1,CHEN Ri-Yao1,ZHENG Xi1,CHEN Xiao1,CHEN Zhen 1,2 1 (College of Chemistry and Materials Science,Fujian Normal University,Fuzhou 350007) 2 (Chemistry Department of Fujian Ningde Teachers College,Ningde 352100);Preparation and Application of Naringin Sensor Based on Molecularly Imprinting Technique[J];Chinese Journal of Analytical Chemistry;2010-01
9 HUANG Jian-xiang,HU Yu-ling,LI Gong-ke*(School of Chemistry and Chemical Engineering,Sun Yat-sen University,Guangzhou 510275);The Development of Selective Coating for Solid Phase Microextraction[J];Journal of Analytical Science;2008-01
10 WU Wu-ai,YIN Zhi-fen,WEI Jing-rui,GUO Man-dong(Department of Chemistry,Shanxi Normal University,Linfen,Shanxi 041004);A Sensitive Mitoxantrone Sensor Based on Molecularly Impringted Electropolymer of o-Aminophemol[J];Journal of Analytical Science;2008-06
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved