STUDY ON SQUARE-WAVE POLAROGRAPHY——II. THEORY OF REVERSIBLE WAVE OBTAINED ON MECHANICAL SQUARE-WAVE POLAROGRAPH
FENG Qiang-Sheng Institute of Metallurgy, Academia Sinica
A theory of reversible wave obtained on the mechanical square-wave polarograph is proposed. 1. The current obtained on plane-electrode is given by ■ 2. The current obtained on dropping-mercury electrode is given by ■ The above theory has been examined experimentally. The theoretical conclusions are in good agreement with experimental data on the reduction of Bi~(3+), Tl~+, Cd~(2+) and U~(VI).