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《Acta Chimica Sinica》 1998-01
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Synthesis and Structural Characterization of V(Ⅳ) and V(Ⅴ)Containing Mixed - Valence Heteropolytungstogermanates

LIU Jing-Fu CHEN Ya-Guang (Department of Chemistry, Northeast Normal University, Changchun, 130024) Hyunsoo So (Department of Chemistry, Sogang University, Seoul 121 -742, Korea) ZHAN Rui-Yun (Changchun Institute of Applied Chemistry,The Chinese Academy of Sciences, Changchun, 130022)  
V(Ⅳ) and V(Ⅴ) containing mixed - valence heteropolytungstogermanates have been prepared by controlled potential reduction of corresponding GeW9V3O407-, their electronic spectra have been recorded. The ESR spectra of one- electron- reduced anions in solution at 340K consist of more than 40 equally spaced lines, showing that the three VO6 octahedra in both α - and β-forms are corner - shared and one of the bridging oxygen atoms is protonated at pH 4.7.
【Fund】: 国家自然科学基金(29271012)
【CateGory Index】: O643.3
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【References】
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1 CHEN Jia,WAN Ying,LI Hexing~*(Department of Chemistry,Shanghai Normal University,Shanghai 200234,China);Ullmann Reaction of Iodobenzene over Pd/NH_2C_3H_6-MCM-41 in Aqueous Medium[J];Chinese Journal of Catalysis;2006-04
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【Co-references】
Chinese Journal Full-text Database 2 Hits
1 LIU Jing-Fu , ZHAO Ben-Liang, LI Jin-Chang, XU Gui-Ying, ZHU Zhi-Ping (Department of Chemistry, Northeast Normal University, Changchun, 130024);Synthesis of α- and β-Cs_4H_3[SiW_3O_(37)Cr_3(H_2O)_3] · xH_2O and Their Catalysis of Epoxidation of Olefin by PhIO[J];Chemical Research In Chinese Universities;1993-03
2 Liu, Jing-Fu~* Zhao, Ben-Liang(Department of Chemistry, Northeast Normal University, Changchun, 130024) Rong, Chao-Ying Pope, M. T. (Department of Chemistry, Georgetown University, Washington DC, 20057, U. S. A.);Synthesis and ~(51)V and ~(183)W NMR Study of α-and β-K_6H[GeW_9V_3O_(40)]·xH_2O[J];Acta Chimica Sinica;1993-04
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1 Li Hexing Zhang Fang (Department of Chemistry,Shanghai Normal University,Shanghai 200234,China);Research Progress in Catalysis for Clean Organic Synthesis in Water-Medium[J];Petrochemical Technology;2008-01
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