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《Acta Chimica Sinica》 1998-01
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Synthesis,Characterization and Luminescence of Tb(Ⅲ) -1 - Phenyl - 3 - methyl - 4 -acyl - 5 - pyrazolone Ternary Complexes

LI Qin ZHOU De - Jian HUANG Chun - Hui YAO Guang - Qing ZHOU Yong - Fen (State Key Laboratory of Rare Earth Material Chemistry and Applications, Peking University, Beijing, 100871) Shigeo Umetani Masakazu Matsui (Institute of Chemical Research , Kyoto University, Uji, Kyoto 611, Japan)  
Four Tb(Ⅲ) ternary complexes with 1 - phenyl - 3 - methyl - 4 - isobutyrylpyrazol -5 - one (HPMIBP) or 1 - phenyl - 3 - methyl - 4 - benzoylpyrazol - 5 - one (HPMBP) as the ligand:Tb(PMIBP)3·2H2O(A1),Tb(PMIBP)3·bpy(A2),Tb(PMBP)3·2H2O(B1)and Tb(PMBP)3·bpy (B2) (where bpy=2,2' - dipyridyl), were synthesized and identified by elemental analysis. They were characterized by UV - Vis, FT - IR spectra and DTA - TG analysis. Their luminescence from both the solid state and solutions were studied and their fluorescence lifetimes were measured from solutions. Results show that the fluorescence intensities of A1 and A2 are three orders magnitude stronger than those for B1 or B2; besides, the fluorescence intensity of A2 and B2 are relatively stronger than those of A1 and B1. The solvents strongly effect on the fluorescence performances of the complexes both in fluorescence intensity and lifetime.
【Fund】: 攀登计划及国家自然科学基金(29601001)
【CateGory Index】: O641.4
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