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《Chemical Research and Application》 2011-02
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Study on the preparation and characterization of sol-gel molecularly imprinted monolithic column

SU Li-qiang,ZHANG Zhong-ying,CHI Da-min(College of Chemistry and Chemical Engineering,Qiqihar Uiniversity,Qiqihar 161006,China)  
Using N-[(tert-Butoxy)carbonyl]-L-tryptophan as the template molecule,3-aminopropyl triethoxysilane as a functional monomer,tetraethyl orthosilicate as crosslinker,a type of molecular imprinted monolithic column was prepared with sol-gel method.The main factors for preparation,such as temperature,acidity and other conditions,were optimized.Pore size distribution of the polymer was characterized by nitrogen adsorption.Polymer contained mesoporous of the template molecule.The average diameter was about 63.Imprinted monolithic column which was preparated was used as analysis of N-Boc-DL-tryptophan and achieved rapid baseline separation for enantiomers.Separation was 1.31.
【Key Words】： molecularly imprinted polymers monolithic column sol-gel method high performance liquid chromatography
【Fund】： 黑龙江省自然科学基金资助项目(B200911)
【CateGory Index】： O657.7
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