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《Journal of Huaiyin Teachers College(Natural Science Edition)》 2013-01
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Synthesis,Crystal Structure and Photoluminescence Property of A Supramolecular Compound [Zn(H_2BTC)_2(phen)]

SHAO Shuai1,ZHAO Hui-chao1,TIAN Jing2,CHEN Xiao-yu2,ZHU Yu-lan1,2(1.Faculty of Chemistry,Northeast Normal University,Changchun Jilin 130024,China)(2.School of Chemistry and Chemical Engineering,Huaiyin Normal University,Huaian Jiangsu 223300,China)  
Under hydrothermal conditions,the reaction of ZnSO4·7H2O with benzene-1,3,5-tricarboxylate(H3BTC) and 1,10-phenanthroline(phen) gave a new supramolecular compound,[Zn(H2BTC)2(phen)].The title compound crystallize in monoclinic system with C2/c space group.Crystal cell parameters are a=9.917(2) A,b=15.984(3) A,c=16.673(3) A.〗,α=90.00°,β=94.607(4)°,γ=90.00°,V=2634.4(9) A3,Z=4.The Zn(II) center in the title compound is six-coordinated,forming a distorted octahedral geometry.The compound presents a 3D supramolecular structure through O—H…O and C—H…O hydrogen bonds.Photoluminescence measurements indicate that the compound has good photoluminescence property.
【Fund】: 国家自然科学基金资助项目(20671038);; 江苏省低维材料化学重点建设实验室开放课题(JSKC11098)
【CateGory Index】: O641.4
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1 MA Feng1,2,ZHAO Lian-hua1,CHEN Zhao-xiang2,MA Kui-rong2,ZHU Yu-lan1,2(1.Department of Chemistry,College of Science,Yanbian University,Yanji Jilin 133002,China)(2.School of Chemistry and Chemical Engineering,Huaiyin Normal University,Huaian Jiangsu 223300,China);Hydrothermal Synthesis,Crystal Structure and Fluorescent Property of A Supramolecular Compound [Cu_2(phen)_2(H_2O)_4]·(SO_4)_2[J];Journal of Huaiyin Teachers College(Natural Science);2011-01
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