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《Journal of Jiangsu University(Natural Science Edition)》 2010-05
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Recognition property and mechanism of molecularly imprinted polymers of Apigenin

He Minqiang1,Song Chengcheng1,Chen Yongqiang1,Li Chunxiang1,Cheng Xiaonong2(1.School of Chemistry and Chemical Engineering,Jiangsu University,Zhenjiang,Jiangsu 212013,China;2.School of Material Science and Engineering,Jiangsu University,Zhenjiang,Jiangsu 212013,China)  
The molecularly imprinted polymers with Apigenin as template molecule were prepared by molecular imprinting technique using 2-vinylpyridine as a functional monomer and EDMA as a cross-linker.The non-covalent interaction between Apigenin and 2-vinylpyridine were determined by UV spectrometry.Apigenin imprinted polymer′s binding affinity and selectivity to Apigenin were evaluated by equilibrium adsorption experiments and its adsorption kinetics were observed.The results show that Apigenin imprinted polymer could specially recognize Apigenin molecule through electrostatic interaction and exhibited higher affinity to Apigenin.Scatchard analysis indicated that there were two classes of recognition sites in Apigenin imprinted polymer,which had different affinity to Apigenin.Furthermore,compared to the adsorption behaviors of Apigenin and its analogs,Apigenin imprinted polymer displayed satisfying selectivity.The selective adsorption of Apigenin on MIP could be accomplished in 1.5 h.
【Fund】: 国家自然科学基金资助项目(20877036)
【CateGory Index】: O631.3
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 LU Yan bing, LIANG Zhi wu, XIANG Wei zhong, XU Wei jian  (Chemistry & Chemical Engineering College, Hunan University, Changsha, 410082);Synthesis and Properties Study of Quinine Molecularly Imprinted Polymer[J];JOURNAL OF ANALYTICAL SCIENCE;2000-04
2 MA Hai-le, WANG Chao, LIU Wei-min (School of Biological and Environmental Engineering, Jiangsu University, Zhenjiang, Jiangsu 212013,China);Microwave-assisted extracting of flavonoids from Radix Pueraria[J];Journal of Jiangsu University (National Science Edition);2005-02
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 HONG Yuan-xin et al (Institute of Liberal and Science,Tarum University,Alaer,Xinjiang 843300);Molecular Imprining Technologies for Natural Product Research Active Ingredients Progress[J];Journal of Anhui Agricultural Sciences;2008-21
2 HAO Ming-yan,HU Xiao-ling,GUAN Ping,YANG Feng(Department of chemisty,College of science,Northwestern Polytechnical University,Xi'an 710072,China);Review of Prepartion of Molecularly Imprinted Membrane[J];Chinese Polymer Bulletin;2007-06
3 HUANG Ai-Ping XU Man-Cai XIAO Gu-Qing XIE Xiang-Lin(College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,P.R.China);Total Flavones in Herba Plantaginis by Microwave-Assisted Extraction[J];Chinese Journal of Spectroscopy Laboratory;2007-03
4 XIAO Gu-Qinga,b LI Wang-Yinga DAI Dianba(Department of Chemistry and Environmental Engineering,Hunan City College,Yiyang,Hunan 413000,P.R.China)b(College of Chemistry and Chemical Engineering,Hunan Normal University,Changsha 410081,P.R.China);Total Flavones in Houttuynia Cordata Thunb by Microwave-Assisted Extraction[J];Chinese Journal of Spectroscopy Laboratory;2007-05
5 HUANG Wei(Yueyang Environment Monitoring Centre,Yueyang,Hunan 414000,P.R.China);Extracting Technology of Total Flavones in Folia Artemisiae Argyi by Microwave-Assisted,Alkali-Solution and Acid-Isolation[J];Chinese Journal of Spectroscopy Laboratory;2008-04
6 CAI Ling,CHEN Xiao-qing*,YU Jun,Tong Xing(Department of Chemistry and Chemical Engineering,Central South University,Changsha 410083,Hunan,China);Microwave Extraction of Total Flavonoids from Polygonum Hydropiper L.[J];Guangzhou Chemistry;2007-04
7 LI Li~1, WU Wen-xiang~2, LI Zhi-wei~3 (1.Light Industry Branch,Hebei Polytechnic University,Hebei Tangshan 063020,China;2.Center of Continued Education,Langfang Teachers College,Hebei Langfang 065000,China;3.Center for Molecular Science,Institute of Chemistry,Chinese Academy of Science,Beijing 100080,China);The Adsorption Characteristic of Cefaclor-imprinted Polymer[J];;2005-05
8 LIU Yaochi 1,2,XIANG Weizhong1 and XU Weijian 1(1Chemistry and Chemical Engineering College,Hunan University, Changsha 410082,Hunan,China; 2Architecture Engineering and Resource Environment College,Nanhua University, Hengyang 421001,Hunan,China);APPLICATIONS AND PROGRESS OF MOLECULAR IMPRINTING TECHNOLOGY IN SOLID PHASE EXTRACTION[J];Journal of Chemical Industry and Engineering(China);2004-10
9 LI Wang-ying,WANG Jiao-liang(Department of Chemistry and Environment Engineering,Hunan City University,Yiyang,Hunan 413000,China);Extracting Technology of the Total Flavones from Andrographis by Microwave[J];Journal of Hunan City University(Natural Science);2008-04
10 XU Wei-jian~(1,2),LIU Yu-tang~(1,2),XIANG Wei-zhong~(1,2),XIONG Yuan-qin~(1,2) ,LU Yan-bing~(1,2),LIU Hui-jun~(1,3) (1.College of Chemistry and Chemical Engineering, Hunan Univ,Changsha410082,China; 2. Institute of Polymer Research, Hunan Univ, Changsha410082,China; 3.College of Chemistry and Chemical Engineering,Nanhua Univ,Hengyang421001,China);Synthesis and Characterization of L-Phe Molecularly Imprinted Polymers[J];Journal of Hunan University (Natural Science);2004-04
【Co-references】
Chinese Journal Full-text Database 10 Hits
1 ZHOU Hui~1,LU Xiang-yang~1,TIAN Yun~1,HUANG Cheng-jiang~2(1 Laboratory of Biochemistry&Fermentation Engineering,HNAU,Changsha 410128;2 Yunnan Tobacco Academic Agricultural Institute,Yuxi 653100,China);Advances in Studies on Chemical Constituents and Pharmacological Activities of Apium L.[J];Amino Acids & Biotic Resources;2006-01
2 FU Ruo-nong(Department of Chemistry,Beijing Institute of Technoligy,Beijing 100081);Advances on SPE-chromatography in China in recent two years[J];Chinese Journal of Analysis Laboratory;2007-02
3 ZHONG Shi-an,HE Guo-wen,LEI Qi-fu and HUANG Ke-long(College of Chemistry and Chemical Engineering,Central South University,Changsha 410083);Study on the solid-phase extraction about catechin active constitutent molecularly imprinted polymer[J];Chinese Journal of Analysis Laboratory;2007-10
4 JIANG Zhong-yi (School of Chemical Engineering and Technology, Tianjin University, Tianjin 300072, China);DESIGN AND PREPARATION OF MOLECULARLY IMPRINTED POLYMERS[J];Polymeric Materials Science & Engineering;2004-03
5 PAN Lang-sheng,LIU Min-min,TIAN Hong-jin,LIU Yue-jin(College of Chemical Engineering,Xiangtan University,Xiangtan 411105,China);Molecular Recognition Characteristics and Solid-phase Extraction Ability of Luteolin Imprinted Polymer[J];Journal of Chemical Engineering of Chinese Universities;2009-02
6 LIU Yaochi 1,2,XIANG Weizhong1 and XU Weijian 1(1Chemistry and Chemical Engineering College,Hunan University, Changsha 410082,Hunan,China; 2Architecture Engineering and Resource Environment College,Nanhua University, Hengyang 421001,Hunan,China);APPLICATIONS AND PROGRESS OF MOLECULAR IMPRINTING TECHNOLOGY IN SOLID PHASE EXTRACTION[J];Journal of Chemical Industry and Engineering(China);2004-10
7 WANG Ke-qin~(1,2) CHEN Jing-ping~2 LUO Jun-wu~1 LIU Zhong-hua~1 CHEN Liang~1(1.Research Center of Natural Products,Hunan Agriculture University,Changsha, Hunan 410128;2.Hunan Institute of Atomic Energy Application in Agriculture,Changsha,Hunan 410125);DETERMINATION OF APIGNIN CONTENT FROM CELERY EXTRACTION BY HPTLC[J];Journal of Nuclear Agricultural Sciences;2008-01
8 Bao Guang-liang, Zhuang Yun-long (School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200072);Progress of Molecular Imprinting Technique[J];Chemical Sensors;2003-01
9 Shi Ruixue\+* Guo Chenghai Zou Xiaohong Zhu Chunye Zuo Yanjun Deng Yundu (Research Institute of Chemical Defence, Beijing 102205, China);The Development of Research in Molecular Imprinting Technique[J];Progress In Chemistry;2002-03
10 WANG Xue-jun,XU Zhen-liang~*,BING Nai-ci(Chemical Engineering Research Center,East China University of Science and Technology,Shanghai 200237,China);Concept of Imprinting Efficiency and Recent Progress of Molecular Imprinting[J];Chemical World;2007-04
【Secondary Citations】
Chinese Journal Full-text Database 9 Hits
1 YANG Ming-yi SHI Jing-song 1 SUN Xiao-ming 1 (Department of Biology,Changde Teachers' University,Changde Hunan,415003) (1 Institute for Utilization of Wild Plant,Nanjing Jiangsu,210000);FURTHER PROCESS AND UTILIZATION OF THE ROOT OF KUDZN VINE[J];Journal of Changde Teachers University;2001-01
2 Meng Zihui, Wang Qinghai, Zhu Daoqian, Zhou Liangmo (Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116012);Application of Molecular Imprinting in Chira1 Separation[J];Chinese Journal of Analytieal Chemistry;1997-03
3 ZHOU Jie, HE Xi Wen *, YANG Wan Long, SHI Hui Ming (Department of Chemistry, Nankai University, Tianjin, 300071);Studies on Character of Adsorption and Recognition of Etharidine Template Polymer[J];CHEMICAL RESEARCH IN CHINESE UNIVERSITIES;1998-09
4 Ding Lijun, Wu Zhenhui, Cai Chuanghai (Department of Biology and Chemistry, Hanshan Normal Institute, Chaozhou, Guangdong 521041, China);Extraction of Flavonoid From Pagodatree Flower[J];Transactions of The Chinese Society of Agricultural Engineering;2002-01
5 Pan Jian Chen Qiang Wang Guoxia Zhang Jian Xie Huiming ( Hefei University of Technology, Hefei);Optimum Extracting Technology of Flavonoids in Radix Puerariae[J];TRANSACTIONS OF THE CHINESE SOCIETY OF AGRICULTURAL ENGINEERING;1998-04
6 Chen Meng, Yuan Dongxing, Xu Pengxiang(Environmental Science Research Center, Xiamen University, Xiamen 361005);Research Progress on Microwave Extraction[J];JOURNAL OF INSTRUMENTAL ANALYSIS;1999-02
7 Wang Guangci;Chen Zongdao;Bao Xianjin;Tang Xiaofeng(College of Food Sciences.Southwest Agricultural University,Chongqing 630716);MICROSCOPS SHAPE AND POPULAR PROPERTIES OF PUERAKIA LOBATA OHWI STARCH[J];JOURNAL OF SOUTHWEST AGRICULTURAL UNIVERSITY;1996-01
8 ZHAO Hao ru 1, GAO Feng xiang 2 1. China Pharmaceutical University, Nanjing 210038, China;2. Henan School of Medicine and Pharmacy, Kaifeng 475001, China);Study on Methods of Extraction of Flavonoids in Radix Puerariae[J];CHINESE TRADITIONAL PATENT MEDICINE;2000-11
9 WANG Juan, SHEN Ping-Niang, SHEN Yong-JiaNational Engineering Research Center far Traditional Chinese Medicine, Shanghai 201203, China; Institute ofChemical and Pharmaceutical ECUST, Slwnghai 200237, China;Study on Microwave-assisted Extraction of Active Constituents in Radix Puerariae[J];Journal of China Pharmaceutical University;2002-05
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