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《Fine Chemicals》 2007-02
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Performance of S-Naproxen Molecularly Imprinted Polymers Prepared by Different Functional Monomers

MA Juan-juan~1,WANG Xin-long~2,XU Xing-you~1(1.Department of Chemical Engineering,Huaihai Institute of Technology,Lianyungang 222005,Jiangsu,China;2.Department of Chemical Engineering,Nanjing University of Science and Technology,Nanjing 210094,Jiangsu,China)  
Using S-naproxen as template,molecularly imprinted polymers P1,P2 and P3 were synthesized by different functional monomers,acrylamide(AM),methacrylic acid(MAA) and N-vinylpyrrolidone(NVP) respectively.By means of UV spectroscopy and computational approach,interaction between the template molecule and functional monomer was studied.The binding energy of the pre-polymerization was calculated by use of PM3 method.Binding isotherms reveal that when the concentration of substrate is 0.1 mmol/L,the amounts of S-naproxen bound to P1,P2 and P3 are 0.360,0.305 and 0.150 μmol respectively.The order of binding capacity of the three kinds of molecularly imprinted polymers is P1P2P3.The results show a positive correlation between the binding quantities and binding energy.
【Key Words】： molecularly imprinted polymers functional monomers computational approach binding capacity
【CateGory Index】： O631.3
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【Co-citations】
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1 Hu Xiaogang~(1,2),Li Gongke~(*1)~1(School of Chemistry and Chemical Engineering,Sun Yat-sen University, Guangzhou 510275)~2(School of Chemistry and Environment,South China Normal University,Guangzhou 510631);Application of Molecular Imprinting Technique in Sample Pretreatment[J];Chinese Journal of Analytical Chemistry;2006-07
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