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《Acta Mineralogica Sinica》 2007-01
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MEASUREMENT AND MECHANISM OF LAYER CHARGE OF PHYLLOSILICATE WITH EXPANSIVE LAYERS

SUN Hong-juan1,2,PENG Tong-jiang1,LIU Ying2(1.Institute of Mineral Materials & Application,Southwest University of Science and Technology Mianyang,Sichuan 621010,China;2.College of Materials Science and Engineering,Sichuan University,Chengdu 610065,China)  
Based on the numbers of layer charge of phyllosilicate with expansive layers(PSEL),expansive layers are classified as montmorillonite layers and vermiculite layers.The origin and type of layer charge of PSEL is discussed.The measurement methods and characterization of layer charge of PSEL are presented.The measurement principle and the crystal-chemical formula method,the cation exchange capacity method and alkyl ammonium method are discussed.The layer charge of montmorillonite from Santai,Sichuan,is calculated by crystal chemical formula and alkyl ammonium methods.It is significant to study layer charge of PSEL for mineral crystal chemistry.
【Fund】: 国家自然科学基金项目(批准号:40502008)
【CateGory Index】: P574
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