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《Physical Testing and Chemical Analysis(Part B:Chemical Analysis)》 2006-02
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STUDY ON THE PREPARATION AND RECOGNITION PROPERTY OF MOLECULAR IMPRINTED POLYMER OF MYCLOBUTANIL

WU Wen-xiang~1,LI Li~2,LI Zhi-wei~3,YANG Geng-liang~3(1.Hebei Langfang Teachers′ College,Langfang 065000,China;2.College of Light Industry,Hebei University of Science and Engineering,Tangshan 063020,China;3.Center for Molecular Science,Research Institute of Chemistry,Chinese Academy of Sciences,Beijing 100080 China)  
Consecutive roll molecular imprinted polymer(MIP) having specific recognition property was prepared by the in-situ molecular imprinting technique,using myclobutanil as a template.Using MIP as stationary phase in liquid chromatography,the content and composition of the mobile phase,and also its content of acid(e.g.HOAc) showed remarkable effect on the separation efficiency and the retention factor decreased with the increase of acid content.The recognition ability of MIP was studied by comparing the retention factors of MIP using different template(myclobutanil and its analogues) as stationary phase of chromatographic column.The results showed that higher recognition ability and better selectivity were obtained on the columns with rod MIP than on the columns with respective blank polymers.
【Fund】: 河北廊坊师范学院自然科学项目(No.LSZYZ200401)
【CateGory Index】: O633.5
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