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《Membrane Science and Technology》 2008-04
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Study on preparation and separation of cellulose acetate-quinine molecularly imprinted composite membrane

ZHANG Chunjing,ZHONG Shian (School of Chemistry and Chemical Engineering,Central South University,Changsha 410083,China)  
The quinine molecularly imprinted composite membrane was prepared by using porous cellulose acetate membrane as support,and the selective binding properties and separation capacity of the membranes were investigated.The results showed that the quinine molecularly imprinted composite membrane had high binding capacity for quinine,the binding amount Q for quinine was 20.6 μmol/g and separation factor was 5.6 for quinine/cinchonine.Permeation experiment results showed that permeation rate of cinchonine through quinine molecularly imprinted composite membrane was higher than that of quinine,the permeation mechanism corforms to the "dissolution-diffusion" model of membrnae permeation.
【Key Words】： cellulose acetate membrane quinine molecularly imprinted composite membrane separation
【Fund】： 湖南省自然科学基金资助项目(06JJ4117);; 中国博士后科学基金项目(20040350648)
【CateGory Index】： TB383.2
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