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《Journal of Nantong Institute of Technology(Natural Science)》 2002-01
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Synthesis of Dioctyl Maleate by Solid Super Acid SO_4~(2-)/ZrO_2 Catalyst

HUA Ping,ZHU Guo-hua,LI Jian-hua,SHA Zhao-lin(Nantong Institute of Technology,Nantong226007,China)  
Solid super acid catalyst SO 42- /ZrO 2 was prepared and used in synthesizing dioctyl maleate and was compared with sulfuric acid and p-toluene sulfonic acid.The results showed that the solid super acid SO 42- /ZrO 2 catalyst had splen-did catalytic activity and could be reused for the synthesis of dioctyl maleate,immersing10hours in1mol /L sulfuric acid solution,baking2hours at550°C.The yield of dioctyl meleate was over97.4%.
【Fund】: 南通市科委基金项目(A2001029)
【CateGory Index】: TQ426
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