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《Journal of Nantong University(Natural Science Edition)》 2013-04
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Components and Formation Pathway of SOF in Diesel/Methanol Combustion Emission Particulates

ZHAO Yang;WANG Zhong;LI Ming-di;NI Pei-yong;LI Rui-na;School of Automobile and Traffic Engineering,Jiangsu University;  
The soluble organic fraction(SOF) of diesel/methanol combustion particulates was analyzed by gas chromatography/mass spec-trometry(GC/MS) and thermogravimetry/difference synchronization analyzer.The results showed that the quality of SOF in the combustion particulate and the weight loss rate peak decrease with the increasing methanol blending ratio.In the three different particulates,about all of SOF were alkanes with straight orbranch chains,the carbon atoms were from 9 to 28 and a number of polycyclic aromatic hydrocarbons and some other organics such as ethylhexyl phthalate.The alkanes in the particulates increased and the polycyclic aromatic hydrocarbons decreased with the increasing methanol blending ratio.H-abstraction acetylene addition mechanism and self-combination reaction of aromatics were the main routes for polycyclic aromatic formation.The alkanes were mainly be formed by diesel and the lubricating oil.
【Fund】: 国家自然科学基金项目(51376083);; 江苏省高校自然科学基金重点项目(10KJA470009);; 江苏省2012年研究生创新计划项目(CXZZ12_0676);; 江苏高校优势学科建设工程资助项目
【CateGory Index】: TK421.5
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