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《Agrochemicals》 2019-01
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Rapid Determination of Avermectin, Imidacloprid and Acetamiprid Residues in Soil by QuEChERS/UPLC-MS/MS

TAN Hua-dong;ZHANG Hui-jie;WU Chun-yuan;Environment and Plant Protection Institute, Chinese Academy of Tropical Agricultural Sciences;Danzhou Scientific Observing and Experimental Station of Agro-Environment, Ministry of Agriculture;School of Resources and Environment, Central China Agricultural University;  
[Aims] A simultaneous analysis method was optimized for the rapid determination of 3 kinds of pesticide residues in tropical soil under rice-vegetables rotation using QuEChERS-ultra-high performance liquid chromatographymass spectrometry(QuEChERS/UPLC-MS/MS). [Methods] The avermectin, imidacloprid and acetamiprid residues were effectively extracted with acetonitrile-0.1% formic acid(by vol), and then were simultaneously detected by external standard method after being purified with the mixed solid-phase dispersion of N-propylethylenedia-mine(PSA) and C_(18).[Results] The linear ranges were over 3 orders of magnitude for 3 kinds of pesticides. Under the three spiked levels of 1.0, 10.0 and 100.0 μg/kg, the average recoveries of the established method were 63.7-101.4%, with the relative standard deviation(RSD) of 0.1-13.6%(n=3). The limits of detection(LODs, S/N=3) of the established method were0.06-0.26 μg/kg, and also the limits of quantification(LOQs, S/N=10) were 0.21-0.89 μg/kg, which were all lower than concentration of the maximum residual limits for pepper recommended from China and UN. [Conclusions] The established method was rapid, easy operation, good sensitivity and reproducibility, could meet actual sample requirements for detection of pesticide residues.
【Fund】: 海南省重大科技计划(ZDKJ2017002);; 中国热带农业科学院环境与植物保护研究所项目结余经费自主选题专项(hzsjy2018003)
【CateGory Index】: O657.63;X833
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