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《Journal of Synthetic Crystals》 2006-01
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Orientation and Distortion of Anionic Coordination-polyhedra in Crystals and the Piezoelectric and Ferroelectric Properties

ZHONG Wei-zhuo,ZHANG Xue-hua,LUO Hao-su,HUA Su-kun(Shanghai Institute of Ceramics,Chinese Academy of Sciences,Shanghai 201800,China)  
The orientation and distortion of anionic coordination-polyhedra in piezoelectric and ferroelectric crystals are studied in this article.It was put forward that the orientation of the same anionic coordination-polyhedra is consistent in piezoelectric crystal,and that the distortion of anionic coordination-polyhedra is accompanied by paraelectric-ferroelectric phase transition in ferroelectric crystal.The mechanism of phase transitions in ferroelectrics was discussed through this basic process.
【Fund】: 国家自然科学基金(No.50272075 No.50432030和No.50331040);; 国家863高新技术项目(No.2002AA325130);; 中国科学院上海硅酸盐研究所创新基金(SCX200411);; 中国科学院创新工程(KJCXZ-SW-105-03)资助项目
【CateGory Index】: O74
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