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《Journal of Synthetic Crystals》 2015-01
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Effects of PEDOT∶ PSS Doping on Performance of Polymer Solar Cells

YAN Hui-min;GUO Ying;ZHU Bing-jie;LIU Gui-lin;ZHU Hua-xin;LI Guo-hua;School of Science,Jiangnan University;School of Internet of Things,Jiangnan University;Jiangsu (Suntech) Institute for Photovoltaic Technology;  
The PEDOT∶ PSS films were optimized using various volumes of dimethyl sulfoxide(DMSO)and glycerol solution as dopants,respectively. The effects of DMSO and glycerol in PEDOT∶ PSS films were investigated. Besides,PSCs used the optimized PEDOT∶ PSS films as anode buffer layer had been researched. The results show that the conductivity of the doped PEDOT ∶ PSS films improve obviously.The changes of optic property and surface roughness indicate that the increase of conductivity of DMSOdoped PEDOT∶ PSS films is related to the decreased size of PEDOT ∶ PSS phase separation; while the increase of conductivity of glycerol-doped PEDOT ∶ PSS films results from the PEDOT ∶ PSS chain conformational change. The highest PCE values of 3. 79% and 2. 70% were obtained using 3% DMSOdoped PEDOT ∶ PSS and 3% glycerol-doped PEDOT ∶ PSS as anode buffer layer respectively,which increased 5. 65 times and 4. 02 times compared with the undoped cell.
【Fund】: 高等学校学科创新引智计划(111计划)
【CateGory Index】: TM914.4
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