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《Journal of Synthetic Crystals》 2015-01
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Structure and Fluorescent Property of 2D Coordination Polymer{[Eu(pdc)(ox)_(0.5)(H_2O)_4]·2H_2O}_n

WANG Hong-sheng;XIA Jun;ZHANG Wan-qiang;School of Chemistry and Chemical Engineering,Xuchang University;School of Environmental and Chemical Engineering,Tianjin Polytechnic University;  
A 2D rare earth europium coordination polymer { [Eu(pdc)(ox)0. 5(H2O)4]·2H2O}n(1)(H2pdc= 2,4-pyridinedicarboxylic acid; ox = oxalate anion) had been synthesized using europium chloride reacting with 2,4-pyridinedicarboxylic acid by hydrothermal method. Oxalate anions is from the decomposing of part of2,4-pyridinedicarboxylic acid. X-ray diffraction analysis of single crystal shows that the coordination polymer is crystallized in monoclinic system,P121 /c1(No. 14) space group. The cell parameters are as follows: a =1. 53047(15) nm,b = 1. 10973(9) nm,c = 0. 85494(15) nm,β = 102. 81(1) °,α = γ = 90°. Eu3 +is ninecoordinated and each Eu3 +coordinates with a pdc anion,an ox anion and four water molecules. The pdc anion connects two Eu3 +ions by μ2-bridge way with the 2-carboxyl group. The nitrogen atom on pyridyl also coordinates to one Eu3 +,but the 4-carboxyl group does not coordinate with Eu3 +ion. Each ox anion connects two Eu3 +by chelating way. A rare 2D zigzag layer is formed by the connections of Eu3 +with pdc and ox aions.The complex exhibits intense characteristic luminescence of Eu3 +with excitation of UV-rays. TG analysisshows the complex has good thermal stability.
【Fund】: 河南省科技厅重点科技(132102210263);; 国家自然科学基金(21101113)
【CateGory Index】: O641.4;O631.24
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