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《Journal of Synthetic Crystals》 2015-01
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Structure and Fluorescent Property of 2D Coordination Polymer{[Eu(pdc)(ox)_(0.5)(H_2O)_4]·2H_2O}_n

WANG Hong-sheng;XIA Jun;ZHANG Wan-qiang;School of Chemistry and Chemical Engineering,Xuchang University;School of Environmental and Chemical Engineering,Tianjin Polytechnic University;  
A 2D rare earth europium coordination polymer { [Eu(pdc)(ox)0. 5(H2O)4]·2H2O}n(1)(H2pdc= 2,4-pyridinedicarboxylic acid; ox = oxalate anion) had been synthesized using europium chloride reacting with 2,4-pyridinedicarboxylic acid by hydrothermal method. Oxalate anions is from the decomposing of part of2,4-pyridinedicarboxylic acid. X-ray diffraction analysis of single crystal shows that the coordination polymer is crystallized in monoclinic system,P121 /c1(No. 14) space group. The cell parameters are as follows: a =1. 53047(15) nm,b = 1. 10973(9) nm,c = 0. 85494(15) nm,β = 102. 81(1) °,α = γ = 90°. Eu3 +is ninecoordinated and each Eu3 +coordinates with a pdc anion,an ox anion and four water molecules. The pdc anion connects two Eu3 +ions by μ2-bridge way with the 2-carboxyl group. The nitrogen atom on pyridyl also coordinates to one Eu3 +,but the 4-carboxyl group does not coordinate with Eu3 +ion. Each ox anion connects two Eu3 +by chelating way. A rare 2D zigzag layer is formed by the connections of Eu3 +with pdc and ox aions.The complex exhibits intense characteristic luminescence of Eu3 +with excitation of UV-rays. TG analysisshows the complex has good thermal stability.
【Fund】: 河南省科技厅重点科技(132102210263);; 国家自然科学基金(21101113)
【CateGory Index】: O641.4;O631.24
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【Citations】
Chinese Journal Full-text Database 2 Hits
1 XIE Feng-xia1,ZHANG Xin-xin1,ZHANG Dan1,HUA Min1,ZHANG Feng-xing2(1.School of Environment and Chemical Engineering,Xi'an Polytechnic Univercity,Xi'an 710048,China; 2.School of Chemistry and Materials Science,Northwest University,Xi'an 710069,China);Synthesis,Structure and Kinetic Analysis of New Lanthanide Complexes {Ln_2(m-bdc)_3(H_2O)_2}_n(Ln=Ce,Nd)[J];Journal of Synthetic Crystals;2013-02
2 LI Gong-Chun WANG Hong-Sheng* ZHU Lei SUN Ting HUANG Chang-Long (College of Chemistry and Chemical Engineering,Xuchang University,Xuchang,Henan 461000,China);Synthesis,Crystal Structure and Luminescent Properties of a 2D Sm(Ⅲ) Coordination Polymer[J];Chinese Journal of Inorganic Chemistry;2012-11
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 LI Lai-xing1,2,WU Bing3,ZHANG Yu-chuan1,2(1.College of Chemistry and Chemical Engineering,Anhui University,Hefei 230039,China; 2.Anhui Province High Performance Rubber Materials and Products Laboratory,Hefei 230088,China; 3.Anhui Anda Zhongding Rubber Technology Development Co.,Ltd,Hefei 230088,China);Synthesis and characterization of N,N-dibutyl dithiocarbamate antimony[J];Journal of Anhui University(Natural Science Edition);2012-03
2 Tang Dingxing (Department of Food Engineering, Anhui Institute of Mechanical and Electrical Engineering, 241000, Wuhu, Anhui, PRC) Wang Bo (Lanzhou Institute of Chemical Physics, Cinese Academy of Science, 730000, Lanzhou, PRC);SYNTHESIS AND STUDIES OF TERNARY COMPLEXES OF RARE EARTH ELEMENTS WITH O AMINOPHENOL AND 4 (3,5 DIPHENYL 2 PYRAZOLIN 1 YL) BENZENESULPHONATE ION[J];Journal of Anhui Normal University(Natural Science);1997-01
3 LI Shu-yan1,SHI Hui-min2(1.Anyang Institute of Technology,Anyang 455000,China;2.Zhengzhou Shuqing Medical College,Zhengzhou 450064,China);The Synthesis and Characterization of Pt(Ⅱ) Acenaphthenequinone Thiosemicarbazones Complex[J];Journal of Anyang Institute of Technology;2010-04
4 LIU Shu-man 1,LIU Feng-qi 1,GUO Hai-qing 2,ZHANG Zhi-hua 2 and WANG Zhan-guo 1[KH2D][WT6BX](1 Laboratory of Semiconductor Materials Science,Institute of Semiconductors, The Chinese Academy of Sciences,Beijing 100083,China) (2 State Key Lab;Investigation on Structure and Luminescenc of ZnO∶Tb Nanocrystals[J];Chinese Journal of Semiconductors;2001-04
5 LI Yi~1,ZHANG Lin-sheng~2(1.2 Department of Environmental Engineering,Southeast University,Nanjing?210096,China);Study on the Properties and Mechanism of Carrying Fe 001×7 Modified Resin for Fluoride Removal[J];Environmental Science and Management;2006-06
6 ZHANG\ Jianbo (Department of Technical Physics, Peking University,Beijing,100871) XU\ Zhenhua (College of Chemistry and Molecular Engineering,Peking University,Beijing,100871) CHEN\ Shoushan (Institute of Elemental Organic Chemistry,Nankai University;FT-IR Spectra Study of Dicyclopentadienyl (Bissubstituted Cyclopentadienyl) Dithiocyano of Titanium, Zirconium and Hafnium[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;1999-06
7 LI Hongliang\ GUO Guolin\ GUI Linlin (Institute of Physical Chemistry,Peking University,Beijing,100871) LI\ Chongjia (Harbin Engineering University Department of Chemical Engineering,Harbin,150001);Synthesis and Photophysical Properties of Cyano Bridged Complexes of Ru(Ⅱ)[J];ACTA SCICENTIARUM NATURALUM UNIVERSITIS PEKINESIS;2000-02
8 MO Jian-jun~1 SHI Lin-mei~2 SHU Zeng-nian~1 XIONG Chun-hua~3(1.Department of Chemistry,Lishui College,Lishui 323000,China;2.Lishui Technology College,Lishui 323000,China;3.College of Food Science,Biotechnology and Environmental Engineering,Zhejiang Gongshang University,Hangzhou 310035,China);Sorption behavior of Ag(Ⅰ) on diglycolamidic acid resin[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2006-03
9 YANG BingChu LI WenFang HUANG XiaoZhong DU ZuoJuan(Department of Physical Science and Technology,Central South University,Changsha Hunan 410083,China);Synthesis and structural analysis of beryllium acetylacetonate[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2010-04
10 JIN Ting ZHU TingYu YE Meng KUANG JunYan JING PengFei(National Engineering Laboratory for Hydrometallurgical Cleaner Production Technology,Institute of Process Engineering,Chinese Academy of Sciences,Beijing 100190,China);Physical and chemical properties of circulating fluidized bed sintering flue gas desulfurization ash[J];Journal of Beijing University of Chemical Technology(Natural Science Edition);2010-06
China Proceedings of conference Full-text Database 10 Hits
1 Fang Youling Zhao Wenkuan Huang Lin Kang Junming Yuan Liangjie (Infrared Materials laboratory,Wuhan University,Wuhau,430072,China) (*Department of Chemistry,Wuhan University,Wuhan,430072,China);The Studies On Synthesis of Superfine SrTiO_3 by the Pyrolysis of Peroxide[A];[C];1995
2 Luo Min Cao Chuanbao Wang Hao Zhu Hesun (Research center of materials science,Beijing Institute of Technology,Beijing,100081,China);Preparation of PLZT Ferroelectric Thin Films by Sol-Gel Method and the Effect of Doping on Dielectric Properties[A];[C];1998
3 YU Tai-bao,XU Wei-bing,ZHOU Zheng-fa,REN Feng-mei (Department of Polymer Science and Engineering,Hefei University of Technology,Hefei 230009,China);Synthesis and thermochemical,fluorescence,antibacterial properties of new ternary lanthanum complex La(cin)_2(imi)_2·H_2O[A];[C];2010
4 Sun Tao Li Ke Huang Xingcai Wu Huilu~(1*) School of Chemical and Biological Engineering,Lanzhou Jiaotong University,Lanzhou 730070, China;Synthesis and Characteriz of The C-pivot tripodal ligands Containing Benzimidazolyl and Copper(Ⅱ) Complex[A];[C];2009
5 YIN Li-song CHEN Min-tao HUANG Sheng-xiang ZHOU Ke-sheng (School of Physics Science and Technology,Central South University,Changsha,410083,China);PREPARING NANOMETER RHOMBUS FLAKE MgO AND IT'S DISTORTION OF CRYSTAL LATTICE AND ABNORMAL INFRARED BEHAVIOR[A];[C];2006
6 Xu Peicang,Zhang Xiaoyun and Li Enlin;MINERAL PHYSICAL CHARACTERISTICS OF FOUR KINDS OF PYROXENE STRUCTURE PHASES IN DIFFERENT ROCKS AND THEIR GEOLOGICAL SIGNIFICANCE[A];[C];1988
7 Xu Peicang and Wan Yongqiang (Xi'an Institute of Geology and Mineral Resources,CAGS) Yang Xinghua (Xi'an College of Metallurgy and Architecture) Li Guanghui (Shaanxi Factory of Colour Kinescope);A STUDY OF CRYSTAL AND MOLECULAR FRAMEWORK STRUCTURE IN ZAS SERIES REFRACTORY MATERIALS AND A PROBE INTO IT'S ERODING MECHANISM[A];[C];1990
8 Wang Jun,Xu Zhenhua,~* Zhao Xuan (Department of Chemistry,Peking University,Beijing,100871,China);THE STUDY OF INTERACTIONS OF[CpFe(CO)_2]_2 WITH SURFACE OF ALUMINA AND TITANIA SUPPORTS BY DIFFUSE REFLECTION AND PHOTOACOUSTIC INFRARED SPECTROSCOPY[A];[C];1996
9 Zhang Hanhui Yan Rongsheng Yu Xiufen Li Hongzhen Zhong Chungxiu (Department of Chemistry,Fuzhou University,Fuzhou,350002);Synthesization of Bi(DTC)_2(NO_3)(H_2O) and a Study of Its Spectra and Molecular Structure[A];[C];1996
10 HUANG Li WANG Degui ZHANG Baochuan (Northwest Institute of Nuclear Technology,710024,Xian);SYNTHESES AND SPECTRAL CHARACTERIZATION OF LiPF_6,LiAsF_6 and LiBF_4[A];[C];1996
【Secondary Citations】
Chinese Journal Full-text Database 10 Hits
1 YANG Jun 1, REN Yu 2, XU Yi-Zhuang 1, SU Yun-Lan 1, ZHANG Li 1, LIU Zhi 1, WANG Fan 1, YANG Li-Min 1, WANG Jing 1,3, GAO Hong-Cheng 1, YE Fang 4, WU Jin-Guang 1* (1. College of Chemical and Molecular Engineering, State Key Laboratory of Rare Earth Material Chemistry and Application, Peking University, Beijing 100871, China; 2. Department of Oncology Surgery, the First Hospital of Xi′an Jiaotong University, Xi′an 710049, China; 3. Collge of Stomatology Medicine, Peking University, Beijing 100871, China; 4. Guangzhou Baiyunshan Pharmaceutical Limited Company, Guangzhou 510515, China);Interaction Between DNA and Terbium(Ⅲ)-Ciprofloxacin Fluorescence Complex and New Tissue Staining Method[J];Chemical Research In Chinese Universities;2004-02
2 JIA Tao1, WANG Kai 1,2, BAO Xiao-Ping1, ZHAO Yi-Mei3, LI Zao-Ying 1* (1. College of Chemistry and Molecular Science, Wuhan University, Wuhan 430072, China; 2. Department of Pharmaceutical Technology, Wuhan Institute of Chemical Techology, Wuhan 430074, China; 3. Institute of RHK(Group) Co. Ltd., Wuhan 430070, China);Synthesis of Metal Porphyrins Bonded with Salicylic Acid and Their Interaction with Bovine Serum Albumin[J];Chemical Research In Chinese Universities;2004-09
3 YANG Rui 1,2, HE Shui-Yang 1*, WU Wang-Ting1, SHI Qi-Zhen1, WANG Da-Qi3 (1. Shaanxi Key Laboratory of Physico-Inorganic Chemistry, Department of Chemistry, Northwest University, Xi′an 710069, China; 2. College of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China; 3. Department of Chemistry,Liaocheng University, Liaocheng 252000, China);Crystal Structure, Fluorescence Properties and Thermal Stability of Supra- molecule Complex [Eu(C_(10)H_9N_2O_4)(C_(10)H_8N_2O_4)(H_2O)_3]_2·phen·4H_2O[J];Chemical Research In Chinese Universities;2005-03
4 YANG Yong-li,DENG Yu-heng,NIE Feng-mei,ZHANG Fan,ZONG Rui-faDepartment of Chemistry,Capital Normal University,Beijing 100037,China;Synthesis,Characterization and Fluorescent Property of Terbium Binary and Ternary Complexes with p-Aminohippuric Acid[J];Spectroscopy and Spectral Analysis;2009-09
5 ZHANG Yan-hui,HAO Yan-zhong*,PEI Juan,LI Ying-pin,SUN Bao,REN Ju-jie College of Science,Hebei University of Science and Technology,Shijiazhuang 050018,China;Synthesis and Fluorescence Properties of Europium Complexes with 4-(4-pyridyl formoyl) Benzoic Acid[J];Spectroscopy and Spectral Analysis;2011-01
6 ZHOU He-feng1,2,WANG Hua1,2,ZHANG Ting1,2,CHEN Liu-qing1,2,XU Hui-xia1,2,HAO Yu-ying1,3(1.Key Laboratory of Interface Science and Engineering in Advanced Materials,Taiyuan University of Technology,Ministry of Education,Taiyuan 030024,China;2.College of Materials Science and Engineering,Taiyuan University of Technology,Taiyuan 030024,China;3.College of Science,Taiyuan University of Technology,Taiyuan 030024,China);Synthesis and spectra analysis of terbium(Ⅲ)complexes[J];Journal of Functional Materials;2011-06
7 HUANG, Bo~aZOU, Guo-Lin~*, aYANG, Tian-Ming~b(~a College of Life Sciences, Wuhan University, Wuhan 430072)(~b Department of Chemistry, South-Central University of Nationalities, Wuh an 430074);Studies on the Interaction between Adriamycin and Bovine Serum Albumin[J];Acta Chimica Sinica;2002-10
8 FENG Lin JIANG Chong-Qiu* SHI Jing-Min (College of Chemistry, Chemical Engineering and Materials Science, Shandong Normal University, Jinan 250014);Synthesis, Characterization and Luminescence Properties of Tb~(3+) and Eu~(3+) Ciprofloxacina-cetylacetone Ternary Solid Complex[J];Chinese Journal of Inorganic Chemistry;2007-09
9 LIU Jing WANG Min ZHANG Zhen-Wei XIA Guang-Ming LU Ping SUN Guo-Xin(School of Chemistry and Chemical Engineering,University of Jinan,Jinan 250022,China);Hydrothermal Synthesis,Crystal Structure and Properties of a Eu(Ⅲ) Coordination Polymer Assembled by(-)-2,2′-[Thiophene-2,5-diylbis(carbonylimino)]dipropanoic Acid and 4,4′-Dipyridine[J];Chinese Journal of Inorganic Chemistry;2012-01
10 Guo Dongcai~(1, 2), Shu Wangen~1, Zhou Yue~2, Liu Younian~1 (1. College of Chemistry and Chemical Engineering, Central Southern University, Changsha 410083, China; 2. College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, China);Synthesis and Luminescence Properties of Reactive Ternary Terbium Complexes[J];Journal of The Chinese Rare Earth Society;2004-02
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