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《Journal of Synthetic Crystals》 2015-01
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Synthesis,Crystal Structure and Catalytic Properties of Novel Zn-N Metal Complexes Based on Ethylenediamine Derivatives

LIU Chao;ZHANG Li-li;WANG Dai-lan;YANG Jin-jing;LIU Xin-hua;School of Chemistry and Chemical Engineering,Suzhou University;School of Pharmacy,Anhui Medical University;  
Two novel Zn-N metal complexes [Zn(OAc)2L](L = N,N-dimethylethylenediamine)(1),N,N '-dibenzylethylenediamine(2)) were synthesized with N,N-dimethylethylenediamine and N,N '-dibenzylethylenediamine as ligand,and the structures were characterized and analyzed by1 H NMR,IR,elemental analysis and X-ray single crystal diffraction. The catalytic properties of the complexes in Henry reaction of aromatic aldehydes with nitromethane and the influences of the reaction conditions were studied,and the applicable scope of aromatic aldehydes in Henry reaction with complex as catalyst was discussed. The results show that the complexes can efficiently catalyze the Henry reaction of different aromatic aldehydes with nitromethane under the conditions as follows: methanol as solvent,complex 1 as catalyst mediated by equimolar triethylamine,and catalyst amount for 25mol%.
【Fund】: 国家自然科学基金(21272008);; 宿州学院产学研合作培育基金项目(2014cxy01);; 国家级大学生创新创业训练计划项目(201310379034);; 省级大学生创新创业训练计划项目(AH201410379106 AH201410379113)
【CateGory Index】: O641.4
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