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《JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY》 1995-01
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STUDY ON KINETICS OF METHANOL TO GASOLINE REACTION

Hao Xu; Du Mingxie; Hu Huiming;Huang Zhe; Hu Jienan (Institute of Coal Chemistry,Chinese Academy of Sciences,Taiyuan)  
The methanol to gasoline reaction over ZSM-5 zeolite catalyst was studied inan isothermal integral reactor in the range of temperature(360℃~390℃),pressure(0.1MPa~4.0MPa),and weight space velocity (5.0h ̄-1~11.0h ̄-1). According to the experimental re-sults, some modifications to the kinetic mechanism of MTG proposed by mihail were sug-gested.A new complex reaction network consisting of 50 reactions involving 26 chemicalspecies was proposed.A kinetic model for MTG composed of 26 ordinary differentiai equa-tions was developed.The activation energies and preexponential factors for every reactionswere estimated by regression of experimental data using Powell method followed by Mar-quardt method.The kinetic model was used to predict the MTG reaction and satisfactory a-greement was obtained between the calculated and experimental data.
【CateGory Index】: TQ013.2
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【Co-references】
Chinese Journal Full-text Database 10 Hits
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