Full-Text Search:
Home|Journal Papers|About CNKI|User Service|FAQ|Contact Us|中文
《JOURNAL OF FUEL CHEMISTRY AND TECHNOLOGY》 1998-06
Add to Favorite Get Latest Update

STUDY OF ZEOLITE CATALYSTS FOR SYNTHESIS OF pISOPROPYLANILINE

Chen Jixiang Tang Xianghai Zhu Ruizhi Pan Lurang (Department of Chemistry Nankai University Tianjin)  
The alkylation of aniline with isopropanol to synthesize pisopropylaniline(p-IPA) on zeolite catalysts has been studied Calcination and hydrothermal treatment were adopted to treat HZSM5 The properties of catalysts were evaluated in the fixed bed flow reactor under atmospheric pressure The surface acidity was measured by means of NH 3TPD and pyridineadsorbed IR The relative pore size of HZSM5 was determined by cyclohexane adsorbance The selectivity of pIPA on HZSM5 is higher than that on other zeolites The optimum conditions are: temperature 623~643K, WHSV 1 0 ̄1 3h 1 , aniline/isopropanol(mol/mol)1 0 ̄2 0 The selectivity of pIPA is increased by calcination, steaming and oxide modification of HZSM5 There is higher conversion of aniline at moderate calcination temperature (about 1023K) and steaming temperature (about 723K) Acidic amount, distribution of acidic strength, acidic type and pore size influence the selectivity of pIPA and aniline conversion The strong acidic centers do not benifit the conversion of aniline and the selectivity of pIPA The weaker Br o ¨nsted acid are main active centers for synthesis of pisopropylaniline
【Fund】: 国家重点自然科学基金
【CateGory Index】: TQ426
Download(CAJ format) Download(PDF format)
CAJViewer7.0 supports all the CNKI file formats; AdobeReader only supports the PDF format.
【References】
Chinese Journal Full-text Database 2 Hits
1 CHEN Ji xiang 1,PAN Lü rang 2,JIANG Hao xi 1,ZHANG Ji yan 1 (1.Department of Catalysis Science and Engineering,College of Chemical Engineering and Technology.Tianjin University,Tianjin 300072,China;2.Department of Chemisitry,Nankai University,Ti;REVIEW ON DEVELOPMENT OF CATALYSTS IN MANUFACTURING ISOPROPYLANILINE[J];Science & Technology In Chemical Industry;2001-01
2 ZHANG Peng-fei,YANG Lian-cheng,WANG Jiu-shan(College of Chemical Engineering and Technology, Tianjin University, Tianjin 300072 China);Synthesis and applications of p-isopropylaniline[J];Tianjin Chemical Industry;2003-03
【Citations】
Chinese Journal Full-text Database 2 Hits
1 Pan Lurang Tang Xianghai (Department of Chemistry,Nankai University,Tianjin 300071);STUDIES ON AROMATIZATION OF n HEXANE,n HEPTANE AND METHYLCYCLOPENTANE OVER MODIFIED HZSM-5[J];ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION);1996-01
2 Guo Changwen,Tang Xianghai,Zhu Ruizhi and Pan Lrang(Department of Chemistry,Nankai University,Tianjin 300071);Study of Zeolite Catalysts for Synthesis of p-Isopropylphenol(Ⅰ)[J];PETROCHEMICAL TECHNOLOGY;1998-03
【Co-citations】
Chinese Journal Full-text Database 10 Hits
1 CHEN Jin-si 1,2,HU Xian-guo2(1.Anhui Province Chemical IndustryDesigningInstitute,Hefei 230009,China;2.Institute of Tribology,Hefei University of Technology,Hefei 230009,China);Research Progress of Solid Acid and Alkali Catalysts on Biodiesel Production from WCO[J];Anhui Chemical Industry;2009-01
2 TANG Ding xing, BO Sheng xi (Dept. of Bioch. Engn. Anhui Institute of Mechanical& Electrical Engineering, Wuhu 241000, China);On the thermal decomposition of ammonium iron sulfate and the catalytic activity of the decomposition product for synthesis of tri- n- butyl citrate[J];Journal of Anhui Institute of Mechanical and Electrical Engineering;2001-03
3 WU Dan et al (College of Chemistry and Environmental Science,Guizhou University for Nationalities,Guiyang,Guizhou 550025);The Preparation of Renewable Green Biodisel Energy with Calcium Oxide as Catalyst[J];Journal of Anhui Agricultural Sciences;2008-13
4 ( 1)Department of Applied Chemistry, Beijing University of Chemical Technology, Beijing, 100029; 2) Central Iron & Steel Research Institute, Ministry of Metallurgical Industry, Beijing, 100081);A study of the synthesis of a blue green emitting phosphor[J];JOURNAL OF BEIJING UNIVERSITY OF CHEMICAL TECHNOLOGY;1998-01
5 LIU Yong-gen,DEN Zhi-hong,YANG Yi-wen,WANG Rui-fen,CHEN Hui-zong (Institute of Chemistry, Jiangxi Normal University, Nanchang 330027, China);A New Way of Synthesizing exo-Borneol[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2004-03
6 CHEN Hui-zong,YANG Yi-wen,LIU Yong-gen,WANG Rui-fen,GE Jun-ying,LIU Fang (Institute of Chemistry and Chemical Engineering,Jiangxi Normal University,Nanchang 330027,China);The Catalytic Synthesis of Borneolacetate by Using Nanometer Rare Earth Composite Solid Superacid[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2005-01
7 XIAO Rong-hua,XU Jing-shi(Institute of Chemistry and Chemical Engineering Sciences,Jiangxi Normal University,Nanchang 330027,China);Preparation of Nano Solid Superacid SO_4~(2-)/M_xO_y and Catalyzed Synthesis of n-Butyl Acetate[J];Journal of Jiangxi Normal University (Natural Sciences Edition);2005-05
8 WU Zhi-kun LI Ju-ren (College of Chemistry and Chemical Engineering, Hunan Normal University,Changsha Hunan,410081);SOLID SUPERACIDS OF SO_4~(2-)/M_xO_y AS CATALYSTS IN ESTERIFICATION[J];JOURNAL OF CHANGDE TEACHERS UNIVERSITY;2000-03
9 Guo Zhongwen (Basic Department, Harbin Univetaity of Sciencc and Technology, Harbin 150080);Preparation of the Hydrogen Catalytic Sensor[J];JOURNAL OF TRANSDUCER TECHNOLOGY;1998-03
10 Wei Yingxu, Xu Lei, Qi Yue, Wang Gongwei (Dalian Institute of Chemical Physics, The Chinese Academy of Sciences, Dalian 116023);CHARACTERIZATION OF CRYSTAL Al_2O_3 PREPARED BY MICROWAVE HEATING[J];CHINESE JOURNAL OF CATALYSIS;1999-03
China Proceedings of conference Full-text Database 4 Hits
1 Ling Qiang,Cui Ping,Wang Guanghai (School of Chemistry and Chemical Engineering,Anhui University of Technology,Ma'anshan 243002);Research of the Best Preparation Conditions of SO_4~(2-)/FeV Solid Acid Catalyst in Preparing Humic Acid from Weathered Coal[A];[C];2008
2 DU Wei LI Xiao-gang WU Jun-sheng LI Lei (School of Materials Science and Engineering,University of Science and Technology Beijing,Beijing 100083,China);Study on preparation and properties of reduce-sulfurating agents for fluid catalytic and cracking[A];[C];2007
3 YUAN Shu-jun The Department of Chemical Engineering,Yancheng College of Technology,Yancheng 224003,China;The Catalytic Synthesis of p-Tert-butylphenolby Activated Fe_2O_3[A];[C];2005
4 YIN Shuangfeng~(1*),ZHANG Shuguo~1,WEI Yudan~2,ZHAO Jin~1,AU Chak-Tong~2 (1.College of Chemistry and Chemical Engineering,Hunan University,Changsha 410082 2.Department of Chemistry,Hong Kong Baptist University,Hong Kong);Preparation,characterization and catalytic applications of some novel superbases[A];[C];2010
【Co-references】
Chinese Journal Full-text Database 9 Hits
1 GAO Hui, SHI Jian-gong, CAO Gang , LU Guan-zhong (Beijing Yanshan Petrochemical Corporation. Beijing 100041 .China; East China University of Science & Technology,Shanghai 200237,China);Progress of synthesis technology of cnmene[J];Journal of Chemical Industry & Engineering;2003-06
2 Tang Jing Chen Junru Li Ruixiang Li Xianjun (Department of Chemistry,Sichuan University,Chengdu 610064);STUDIES ON VAPOURPHASE N ALKYLATION OF AROMATIC AMINES[J];CHEMICAL RESEARCH AND APPLICATION;1996-03
3 CHEN Ji xiang 1,PAN Lü rang 2,JIANG Hao xi 1,ZHANG Ji yan 1 (1.Department of Catalysis Science and Engineering,College of Chemical Engineering and Technology.Tianjin University,Tianjin 300072,China;2.Department of Chemisitry,Nankai University,Ti;REVIEW ON DEVELOPMENT OF CATALYSTS IN MANUFACTURING ISOPROPYLANILINE[J];Science & Technology In Chemical Industry;2001-01
4 XIA Tian-xi 1,CHEN Ping 2 (1.Department of Chemical Engineering, Jiansu Institute of Petrochemical Technology, Changzhou 213016,China;2.Changzhou Pesticide Plant,Changzhou 213022,China);Study on the Synthesis of Isoproturon as Herbicides[J];Journal of Jiangsu Institute of Petrochemical Technology;2001-02
5 Yang Shaohua Cui Yingde Chen Xunjun Tu Xing (Faculty of Chemical Engineering and Light Industry, Guangdong University of Technology,Guangzhou 510090);Development of Synthesis and Surface Modification of ZSM-5 Zeolite Molecular Sieves[J];Advances in Fine Fetrochemicals;2003-04
6 Chen Jixiang Tang Xianghai Zhu Ruizhi Pan Lürang (Department of Chemistry,Nankai University,Tianjin 300071);STUDY ON ALKYLATION OF ANILINE WITH ISOPROPANOL ON HZSM 5 SYNTHESIZED BY DIFFERENT METHODS[J];ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION);1999-03
7 Li Dongfan Zhang Yingzhen Tao Longxiang Jin Jun,and Zheng Lubin (Dalin Institute of Chemical Physics,Academia Sinica);Effect of Steam Treatment on Acidity,Activity and Olefine Selectivity of HZSM-5 Zeolites[J];Petrochemical Technology;1988-03
8 ZHU Rui-zhi,CHEN Ji-xiang,TANG Xiang-hai,PAN Lü-rang T6BZ](Department of Chemistry,Nankai University,Tianjin 300071,China)(Department of Chemistry,Nankai University,Tianjin 300071,China);Synthesis of Isopropylaniline over HY Molecular Sieve[J];PETROCHEMICAL TECHNOLOGY;2000-05
9 SUN Hai, LIU Jing, GUO Rusheng 116012,China);The progress of supercritical alkylation[J];Natural Gas Chemical Industry;2003-02
【Secondary References】
Chinese Journal Full-text Database 4 Hits
1 Xu Jiewu1,Cai Zhaosheng2(1.Funing Anqing Chemical Co.,Ltd.,Yancheng 224403; 2.Department of chemical and Biological Engineering,Yancheng Institute of Technology,Yancheng 224051,China);Optimization for the Synthetic Condition of 4-isopropylaniline by Homogeneous Alkylization[J];Guangdong Chemical Industry;2012-05
2 TAN Weiyi,ZHANG Zhihui,CHEN Qun,HE Mingyang(Institute of Petrochemical Technology,Changzhou University,Changzhou 213164,Jiangsu,China);Synthesis of N-propylaniline with the caprolactam ionic liquids as catalysts[J];Chemical Industry and Engineering Progress;2012-04
3 LI Guo-yun~1 CAI Zhao-sheng~2 (1.Fuclear Science & Technology(Suzhou)Co.Ltd.,Suzhou 215008,China; 2.Department of Chemical and Biological Engineering,Yancheng Institute of technology,Yancheng 224003,China);Study on the synthesis of 4-isopropylaniline by homogeneous alkylization[J];Chemical Engineer;2007-05
4 Zhang Pengfei,Zhao Yang,Wang Cong(College of Chemical Engineering and Technology,Tianjin University,Tianjin 300072,China);Synthesis of p-Isopropylaniline[J];Petrochemical Technology;2005-01
【Secondary Citations】
Chinese Journal Full-text Database 4 Hits
1 Guo Xiexian, Tao Longxiang, Xu Yide, Ruan Zhenkui, Huang Jiasheng, Shi Yingzhen, Wang xiaoming & Pan Lurang(Dalian Institute of Chemical Physics, Academia Sinica);MECHANISM OF ISOMERIZATION OF ALKANE OVER PLATINUM-SUPPORTED CATALYST Ⅰ. A "CYCLOPROPANOID" MECHANISM OF ISOMERIZATION OF ALKANE[J];Chinese Journal of Catalysis;1980-02
2 Pan Yun, Yang Xi-yao and Pang Li (Department of Chemistry, Peking University);CHARACTERISTICS,STATES AND REACTIVITY OF DEHYDROCYCLIZATION ACTIVE CENTER OVER Pt-Al_2O_3 CATALYSTS[J];Chinese Journal of Catalysis;1989-01
3 Wang Jingzhong, Pan Lurang and Li Hexuan (Department of Chemistry, Nankai University,Tianjin);Study of the Synthesis and the Acidity of Containing Boron Tz-01 Type Molecular Sieve[J];Chemical Research In Chinese Universities;1988-03
4 Pan Lurang Tang Xianghai (Department of Chemistry,Nankai University,Tianjin 300071);STUDIES ON AROMATIZATION OF n HEXANE,n HEPTANE AND METHYLCYCLOPENTANE OVER MODIFIED HZSM-5[J];ACTA PETROLEI SINICA (PETROLEUM PROCESSING SECTION);1996-01
©2006 Tsinghua Tongfang Knowledge Network Technology Co., Ltd.(Beijing)(TTKN) All rights reserved