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《Journal of Guandong College Petrochemical Technology》 2003-01
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A Study on Kinetics Model of Coal Liquefaction Process

ZOU Gang-ming,LI Hai-bin(1.Maoming College,Maoming 525000,China;2.Taiyuan University of Technology,Taiyuan 030024,China)  
In the paper, the pyrogenation character and kinetics of coal are discussed. From molecule structure of coal, coal reaction character is described by aromatic ring . Kinetics model of coal pyrogenation can be obtained by analysing the data of TGA experiment according to log〔-log(1-a)〕=log(AE/Rφ)-0.054E/T-2.284. The result shows that coal pyrogenation reaction includes three one-order reactions,namely two pyrogenations and one polycondensation. On calculating pyrolysis characteristic values of coal , apparent activation energy(Ea) of various stages, reaction kinetics constant (K), pre-exponent (A) , maximum weightlessness rate(Rm), weight loss percent (F), reaction active index(Ra),they can be regarded as the index of coal pyrolysis reactive activity .The bigger Ra or Rm, the better reactive activity of coal .The value of Tb(initial reaction temperature) and Tf(final reaction temperature) is defined through the curves of TG and DTG . It decides the upper limit of reaction temperature of routine and high temperature rapid liquefaction . Thus, the section of coal liquefaction reaction temperature is 390-480℃ of Yang cun coal and 425-525℃ of Sheng mu coal separately .
【Fund】: 山西省自然科学基金资助 ( 9910 14 )
【CateGory Index】: TQ529
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【Co-references】
Chinese Journal Full-text Database 10 Hits
1 Pan LiminLiu Qun (Changchun University of Earth Sciences, Changchun 130026)(Heilongjiang College of Hydraulics) Chen Chunsheng (Jilin Bureau of Geology and Minenal Resources);DISCUSSION ON THE HYDROCARBONIC GENERATION CAPACITY OF THE MINIMOLECULAR COMPOUNDS IN COAL[J];;1996-03
2 Zhang Dexiang, Gao Jinsheng Zhu Zhipei (Department of Chemical Engineering of Energy Sources);The liquefaction of some chinese low rank coals by hydrogenation in various heavy oils of petroleum[J];;1986-03
3 Gao Jinsheng~(*a), Wu Youqing~a, H. H. Oelert~b and Zhang Peifang~b a: Dept. of Chemical Engineering of Energy Resources, ECUST, CHINA b: Institute of Chemical Technology, TU Clausthal, D-3392 Clausthal-Zellerfeld, GERMANY;Study on Co-Processing of Chinese Low-Rank Bituminous Coals and Petroleum Vacuum Residues[J];;1993-05
4 MA Xiao-yan 1, ZHAO Pu 2, ZHANG Shi-cheng 2 (1.Heilongjiang Institute of Science and Technology,Jixi 158105,China;2.Jixi Coal Mining Bureau,Jixi 158100,China);Discussing about the research of low molecule chemical compound on the effect of liquefaction on coal adding in hydrogen[J];Coal Technology;2001-11
5 Gao Jinsheng and Zhou Xiaping East China University of Chemical Technology,200237 Shanghai;LOW MOLECULAR WEIGHT COMPOUNDS OF COAL AND ITS FUNCTION IN COAL CONVERSION PROCESSES[J];Coal Conversion;1992-03
6 Wang Na ; Sun Cheggong ; Li Baoqing(State Key Laboratory of Coal Conversion, Institute of Coal Chemistry,Chinese Academy of Sciences, 030001 Taiyuan);REVIEW OF THE STUDY ON LOW MOLECULAR WEIGHT COMPOUNDS OF COAL[J];COAL CONVERSION;1997-03
7 Yuan Xinhua; Fan Jian and Qin Zhihong(China Uniuersity of Mining and Technology, 221008 Xuzhou);STUDY ON EXTRACTION YIELD OF COAL IN CARBON DISULFIDE-N-MELTHYL-2-PYRROLIDIN MIXED SOLVENT[J];COAL CONVERSION;1998-02
8 Zhu Xiaosu\ Li Ruying\ Zheng Jianguo\ Huo Weidong and Qian Daoping (Beijing Research Institute of Coal Chemistry, CCRI, 100013 Beijing);THE THEORY ON LIMITATIONS OF DIRECT COAL LIQUEFACTION OIL YIELD AND ITS APPLICATION IN CATALYSTS RESEARCH[J];Coal Conversion;2001-01
9 Sun Linbing\ Zhang Lifang\ Qin Zhihong\ Zong Zhimin and Wei Xianyong (School of Chemical Engineering,China University of Mining and Technology,221008 Xuzhou);ADVANCES IN COAL EXTRACTION WITH CARBON DISULFIDE/N-METHYL-2-PYRROLIDINONE MIXED SOLVENT[J];Coal Conversion;2002-04
10 Liu Zhenxue Wei Xianyong * Zhou Shixue and Wang Hualan ** (School of Chemical Engineering,Shandong University of Science and Technology,250031 Jinan;* School of Chemical Engineering, China University of Mining and Technology,221008 Xuzhou; ** Ji'nan Steel and Iron Corporation,250101 Ji'nan);ADVANCESING COAL OF SOLVENT EXTRACTION STUDIES PART (Ⅰ) ORGANIC SOLVENTS AND THEIR EXTRACTING MECHANISM[J];Coal Conversion;2003-02
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