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《Journal of Guandong College Petrochemical Technology》 2005-01
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A Study on Pseudorotaxane of Cucurbit[n]uril with Alkylane-diamines

YAO Xiao-qing (Maoming College, Maoming 525000, China)  
Inthispaper,wereportself-assemblypseudorotaxaneofcucurbit[n]urilwithalkylanediaminesbyusing1HNMRtechniques.Theexperimentresultsrevealedthatundertheexperimentalcondition,thecucurbit[n=6]urilcaneasilyassembletoformhost-gustcomplexwithsomealkylanediaminesandinvolvewithdifferentstructures.Onthesameinteractionbasis,cucurbit[n=7]urilwithbiggernon-polaritycavityinteractcapabilityisdifferentfromcucurbit[n=6]uril;cucurbit[n=8]urilcanonlyrecognize1,9-diaminodecaneand1,12-diaminododecane.
【CateGory Index】: O621
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